This volume details all the developments in Polyethers and Polyesters over the last decade and catlogs their polymerization, properties, applications, fabrication techniques, safety aspects, and lists suppliers.
Table of Contents1. Engineering and Specialty Thermoplastics: Polyethers and Polyesters
Sabu Thomas and Visakh P. M 1.1 Introduction
1.2 Polyesters Synthesis
1.3 Polyethers
1.3.1 Aromatic Polyethers
1.4 Individual Polyethers and Polyesters and Their Application
1.4.1 Poly (Phenylene Oxide)
1.4.2 Polyether Ether Ketone
1.4.3 Poly(Ethylene Terephthalate)
1.4.4 Poly(Butylene Terephthalate)
1.4.5 Polyesters Containing Cyclohexanedimethanol Units
1.4.6. Liquid Crystal Polyesters
1.4.7 Polylactide
1.4.8 Thermoplastic Copolyester Elastomers (TPEEs)
1.4.9 Polycarbonate (PC)
1.5 New Challenges and Opportunities.
2. Poly(phenylene oxide)
Mong Liang 2.1 Introduction and History
2.2 Monomer
2.3 Polymerization and Mechanism
2.4 Properties
2.5 Compounding and Special Additives
2.6 Processing
2.7 Applications
2.8 Environmental Impact and Recycling
2.9 Recent Developments in Poly Phenylene Oxide Based Blends and Composites and Their Applications.
3. Polyether Ether Ketone
Jinwen Wang 3.1 Introduction and History
3.2 Polymerization and Fabrication
3.3 Properties
3.3.1 Solution Properties
3.3.2 Thermal Properties
3.3.2.1 Melting and Crystallization
3.3.2.2 Crystallization Kinetics
3.3.2.3 Spherulites
3.3.2.4 Decomposition
3.3.3 Mechanical Properties
3.3.3.1 Tensile Properties
3.3.3.2 Fracture Toughness
3.3.3.3 Tensile Creep
3.3.3.4 Compressive Properties
3.3.3.5 Taylor Impact
3.3.3.6 Tribological Behavior
3.4 Chemical Properties
3.5 Environmental Resistance
3.6 Compounding and Special Additives
3.7 Processing
3.8 Applications
3.9 Environmental Impact and Recycling
3.10 Recent Developments in PEEK Based Blends and Composites and Their Applications.
4. Poly(ethylene terephthalate)
B ¯¿½n ¯¿½dicte Lepoittevin and Philippe Roger 4.1 Introduction and History
4.2 Polymerization and Fabrication
4.2.1 First Step: Prepolymerization
4.2.2 Second Step: Polycondensation
4.2.3 Solid-State Polymerization
4.3 Solid-State Properties
4.3.1 Mechanical Properties
4.3.2 Thermal Properties
4.3.3 Gas Barrier Properties
4.3.4 Other Physical Properties
4.4 Chemical Stability
4.4.1 Solubility and Chemical Resistance of PET
4.4.2 Hydrolytic Degradation of PET
4.4.2 Thermal Degradation of PET
4.4.3 Thermo-oxidative Degradation of PET
4.5 Compounding and Special Additives
4.6 Processing
4.6.1 Extrusion
4.6.2 Injection Molding
4.6.3 Blow Molding
4.7 Applications
4.7.1 PET Fibers
4.7.2 PET Films
4.7.3 PET Bottles
4.8 Environmental Impact and Recycling
4.8.1 Generality about PET Recycling
4.8.2 Chemical Recycling of PET
4.8.2.1 Methanolysis
4.8.2.2 Glycolysis
4.8.2.3 Hydrolysis
4.8.2.4 Others methods
4.8.3 Mechanical Recycling
4.8.4 Recent Developments in PET Recycling
4.9 Recent Developments in Poly(ethylene terephthalate) Based Blends and Composites and Their Applications
4.9.1 PET Blends
4.9.1.1 PC/PET blends
4.9.1.2 PP/PET Blends
4.9.1.3 PET/PBT Blends
4.9.2 PET and Layered Silicates Nanocomposites
4.10 Recent Advances in Surface Modi. cation of PET Materials
4.10.1 Surface Modi.cation by Physical Treatment
4.10.2 Chemical Treatment
4.10.3 Grafting Polymerization.
5. Poly(butylene terephthalate) --Synthesis, Properties, Application
Vesna V. Antic--‚¬Ëœ and Marija V. Pergal 5.1 Introduction and History
5.2 Polymerization and Fabrication
5.3 Physical and Chemical Properties
5.4 Processing
5.5 Applications
5.6 Compounding and Special Additives
5.6.1 Colorants and Fillers
5.6.2 Flame-retardant PBT
5.6.3 PBT Composites
5.6.4 PBT Blends
5.6.4.1 PBT/PET Blends
5.6.4.2 PBT/PC Blends
5.6.4.3 Impact-modi.ed PBT Blends
5.6.4.4 PBT/polyamide Blends
5.7 Thermoplastic Polyester Elastomers (TPEE)
5.7.1 PBT/TPEE Blends and Composites
5.8 Environmental Impact and Recycling.
6. Polyesters Based on Cyclohexanedimethanol
A. Mart ¯¿½nez de Ilarduya and S. Mu ¯¿½oz Guerra 6.1. Introduction and History
6.1.1 Monomers
6.1.2 Aliphatic Polyesters and Copolyesters
6.1.3 Aromatic Polyesters and Copolyesters
6.2 Polymerization and Fabrication
6.2.1 Polycondensation in Solution
6.2.2 Melt Phase Polycondensation
6.2.3 Ring Opening Polymerization
6.3 Properties
6.3.1 Thermal properties
6.3.2 Mechanical Properties
6.3.3 Other Properties
6.4 Chemical Stability
6.4.1 Thermal Decomposition
6.4.2 Chemical Degradation
6.5 Compounding and Special Additives
6.6 Processing
6.7 Applications
6.8 Environmental Impact and Recycling
6.9 Recent Developments in Blends and Composites and Their Aplications
6.9.1 Blends
6.9.2 Composites.
7. Bisphenol-A
Piotr Czub 7.1 Introduction and History
7.2 Fabrication Methods
7.3 Mineral Acid Catalysts
7.4 Ion-exchange Resin Catalysts
7.5 Solid Acid Catalysts
7.6 BPA Yield and Selectivity
7.7 BPA Waste Disposal
7.8 Alternative Paths for the BPA Synthesis
7.9 Properties
7.10 Applications
7.11 Environmental and Human Health Impact.
8. Liquid Crystal Polyesters
A.B.Samui and V. Srinivasa Rao 8.1 Introduction and History
8.1.2 Liquid Crystalline Polymers (LCP)
8.1.3 Polyesters
8.1.4 Liquid Crystalline Polyesters (LC Polyesters)
8.2 Polymerization and Fabrication
8.2.1 Polymerization
8.2.1.1 Co-Polyester
8.2.1.2 Side Chain LC Polyester
8.2.1.3 LC Elastomer
8.2.1.4 Enzymatic Method of LC Polyester Synthesis
8.2.1.5 Microwave-Assisted LC Polyester Synthesis
8.2.2 Fabrication
8.2.2.1 LC Polymer Blend
8.2.2.2 LC Polyester Composite
8.2.2.3 Polymer Dispersed Liquid Crystal
8.3 Properties
8.3.1 Mechanical Properties
8.3.1.1 Type -1 Copolyester
8.3.1.2 Type -2 Copolyester
8.3.1.3 Type -3 Polyester
8.3.2 Solubility
8.3.3 Thermal Property
8.3.4 Transition Temperatures and Textures
8.3.5 Crystallization
8.3.6 Morphology and Related Microstructure
8.3.7
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