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Doping in Conjugated Polymers

By Pradip Kar
Copyright: 2013   |   Status: Published
ISBN: 9781118573808  |  Hardcover  |  
174 pages | 52 illustrations
Price: $125 USD
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One Line Description
An A-to-Z of doping including its definition, its importance, methods of measurement, advantages and disadvantages, properties and characteristics—and role in conjugated polymers

Audience
The book will interest a broad range of researchers including chemists, electrochemists,biochemists, experimental and theoretical physicists, electronic and electrical engineers,polymer and materials scientists. It can also be used in both graduate and upper-level undergraduate courses on conjugated polymers and polymer technology.

Description
The versatility of polymer materials is expanding because of the introduction of electroactive behavior into the characteristics of some of them. The most exciting development in this area is related to the discovery of intrinsically conductive polymers or conjugated polymers, which include such examples as polyacetylene, polyaniline, polypyrrole, andpolythiophene as well as their derivatives. “Synmet” or “synthetic metal” conjugated polymers,with their metallic characteristics, including conductivity, are of special interest to researchers. An area of limitless potential and application, conjugated polymers have sparked enormous interest, beginning in 2000 when the Nobel Prize for the discovery and development of electrically conducting conjugated polymers was awarded to three scientists: Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa.

Conjugated polymers have a combination of properties—both metallic (conductivity) and polymeric; doping gives the conjugated polymer’s semiconducting a wide range of conductivity, from insulating to low conducting. The doping process is a tested effective method for producing conducting polymers as semiconducting material, providing a substitute for inorganic semiconductors.

Doping in Conjugated Polymers is the first book dedicated to the subject and offers a comprehensive A-to-Z overview. It details doping interaction, dopant types, doping techniques,and the influence of the dopant on applications. It explains how the performance of doped conjugated polymers is greatly influenced by the nature of the dopants and their level of distribution within the polymer, and shows how the electrochemical, mechanical, and optical properties of the doped conjugated polymers can be tailored by controlling the size and mobility of the dopants counter ions.

The book also examines doping at the nanoscale, in particular, with carbon nanotubes.

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Author / Editor Details
Pradip Kar obtained his PhD in 2009 from the Indian Institute of Technology, Kharagpur, India. He has also worked in LPPI, Université de Cergy-Pontoise, France for about one year. He is currently an Assistant Professor in the Department of Applied Chemistry, Birla Institute of Technology, Ranchi, India. He has published more than 20 research papers in peer-reviewed journals.

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Table of Contents
Preface
1 Introduction to Doping in Conjugated Polymer
1.1 Introduction
1.2 Molecular Orbital Structure of Conjugated Polymer
1.3 Possibility of Electronic Conduction in Conjugated Polymer
1.4 Necessity of Doping in Conjugated Polymer
1.5 Concept of Doping in Conjugated Polymer
1.6 Doping as Probable Solution

2 Classification of Dopants for the Conjugated Polymer
2.1 Introduction
2.2 Classification of Dopant According to Electron Transfer
2.3 Classification of Dopant According to Chemical Nature
2.4 Classification of Dopant According to Doping Mechanism

3 Doping Techniques for the Conjugated Polymer
3.1 Introduction
3.2 Electrochemical Doping
3.3 Chemical Doping
3.4 In-situ doping
3.5 Radiation-Induced Doping or Photo Doping
3.6 Charge Injection Doping

4 Role of Dopant on the Conduction of Conjugated Polymer
4.1 Introduction
4.2 Charge Defects within Doped Conjugated Polymer
4.3 Charge Transport within the Doped Conjugated Polymer
4.4 Migration of Dopant Counter Ions

5 In ¯¬€šuence of Properties of Conjugated Polymer on Doping
5.1 Introduction
5.2 Conducting Property
5.3 Spectroscopic Property
5.4 Electrochemical Property
5.5 Thermal Property
5.6 Structural Property

6 Some Special Classes of Dopants for Conjugated Polymer
6.1 Introduction
6.2 Iodine and Other Halogens
6.3 Halide Doping
6.4 Protonic Acid Doping
6.5 Covalent Doping

7 In ¯¬€šuence of Dopant on the Applications of Conjugated Polymer
7.1 Introduction
7.2 Sensors
7.3 Actuators
7.4 Field Effect Transistor
7.5 Rechargeable Batteries
7.6 Electrochromic Devices
7.7 Optoelectronic Devices
7.8 Others Applications

8 Recent and Future Trends of Doping in Conjugated Polymer
8.1 Introduction
8.2 Doping of Nanostructured Conjugated Polymer
8.3 Doping in Conjugated Polymer Nanocomposite
8.4 Future Trends

References

Index


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BISAC SUBJECT HEADINGS
TEC 055000: Technology & Engineering/Textile & Polymers
TEC009010: Technology & Engineering/Chemical & Biochemical
SCI013040: Science:Chemistry/Organic
 
BIC CODES
TDCP: Plastics and Polymers Technology Plastics & Polymer Technology
TDCB: Chemical Engineering

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