The only comprehensive in-depth coverage of reverse osmosis and the benefits of its use in industrial water management.
Table of ContentsContents
Preface xvii
PART 1 FUNDAMENTALS
1 Introduction and History of Development 3
1.1 Introduction 3
1.1.1 Uses of Reverse Osmosis 3
1.1.2 History of Reverse Osmosis Development 5
1.1.3 Recent Advances in RO Membrane Technology 9
1.1.4 Future Advancements 12
References 12
2 Reverse Osmosis Principles 15
2.1 Osmosis 15
2.2 Reverse Osmosis 16
2.3 Dead-End Filtration 17
2.4 Cross-Flow Filtration 18
3 Basic Terms and Defi nitions 21
3.1 Reverse Osmosis System Flow Rating 21
3.2 Recovery 21
3.3 Rejection 23
3.4 Flux 26
3.5 Concentration Polarization 27
3.6 Beta 29
3.7 Fouling 30
3.8 Scaling 33
3.9 Silt Density Index 35
3.10 Langelier Saturation Index 38
References 39
vii
viii Contents
4 Membranes
4.1 Transport Models 41
4.1.1 Solution-Diffusion Model
(non-porous model) 42
4.1.2 Solution --Diffusion Imperfection
Model (porous model) 44
4.1.3 Finely-Porous Model
(porous model) 45
4.1.4 Preferential Sorption --Capillary
Flow Model (porous model) 45
4.1.5 Phenomenological Transport
Relationship (Irreversible
thermodynamics) 46
4.2 Membrane Materials 46
4.2.1 Cellulose Acetate
Membranes----Asymmetric
membranes 47
4.2.2 Polyamide and Composite
Membranes 51
4.2.2.1 Linear Aromatic Polyamide
Membranes 51
4.2.2.2 Composite Polyamide Membranes 52
4.2.3 Improvements to Polyamide,
Composite Membranes 56
4.2.4 Other Membrane Materials 58
4.3 Membrane Modules 58
4.3.1 Plate and Frame Modules 59
4.3.2 Tubular Modules 60
4.3.3 Spiral Wound Modules 61
4.3.4 Hollow Fine Fiber Membrane
Modules 72
4.3.5 Other Module Confi gurations 74
4.4 Commercially-Available Membranes 76
4.4.1 Seawater Membranes 76
4.4.2 Brackish Water Membranes 78
4.4.2.1 Low-Energy Membranes 79
4.4.2.2 High-Rejection Membranes 79
4.4.2.3 Low-Fouling Membranes 79
Contents ix
4.4.2.4 Low-Differential-Pressure
Membrane Modules 80
4.4.2.5 High-Productivity Membrane
Modules 81
4.4.2.6 Other Membrane/Module
Types 81
References 83
5 Basic Flow Patterns 85
5.1 Arrays 85
5.2 Recycle 89
5.3 Double Pass 90
5.4 Multiple Trains 93
6 Reverse Osmosis Skids 95
6.1 Cartridge Filters 97
6.2 Reverse Osmosis Feed Pumps 100
6.3 Pressure Vessels 106
6.4 Manifolding----Materials of Construction 114
6.5 Instrumentation 114
6.6 Controls 116
6.7 Data Acquisition and Management 118
6.8 Reverse Osmosis Skid 120
6.9 Auxiliary Equipment 120
6.10 Other Design Considerations 121
6.10.1 Access to Profi le and Probe
RO Membranes 121
6.10.2 Interstage Performance Monitoring
Instrumentation 121
6.10.3 Stage-by-Stage Membrane Cleaning 122
References 122
PART 2 PRETREATMENT
7 Water Quality Guidelines 125
7.1 Suspended Solids 125
7.2 Microbes 127
7.3 Organics 128
7.4 Color 129
x Contents
7.5 Metals 130
7.6 Hydrogen Sulfi de 131
7.7 Silica 132
7.8 Calcium Carbonate 134
7.9 Trace Metals----Barium and Strontium 136
7.10 Chlorine 136
7.11 Calcium 137
7.12 Exposure to Other Chemicals 139
References 139
8 Techniques and Technologies 141
8.1 Mechanical Pretreatment 142
8.1.1 Clarifi ers 142
8.1.1.1 Solids-Contact Clarifi ers 144
8.1.1.2 Inclined-Plate Clarifi ers 145
8.1.1.3 Sedimentation Clarifi ers 148
8.1.1.4 Chemical Treatment for Clarifi ers 149
8.1.2 Multimedia Pressure Filters 151
8.1.3 High-Effi ciency Filters 153
8.1.4 Carbon Filters 157
8.1.5 Iron Filters 160
8.1.5.1 Manganese Greensand Filters 161
8.1.5.2 BIRM ‚® Filters 162
8.1.5.3 Filox Filters 163
8.1.5.4 Other Iron Removal Media 163
8.1.6 Sodium Softeners 164
8.1.7 Spent Resin Filters 167
8.1.8 Ultraviolet Irradiation 168
8.1.9 Membrane 169
8.2 Chemical Pretreatment 170
8.2.1 Chemical Oxidizers for Disinfection of
Reverse Osmosis Systems 171
8.2.1.1 Chlorine 171
8.2.1.2 Ozone 176
8.2.1.3 Hydrogen Peroxide 177
8.2.2 Antiscalants 177
8.2.3 Sodium Metabisulfi te 180
8.2.4 Non-Oxidizing Biocides 182
8.2.4.1 Sodium Bisulfi te 182
Contents xi
8.2.4.2 DBNPA 182
8.2.4.3 Other Non-Oxidizing Biocides 183
8.3 Combination Mechanical Plus Chemical
Pretreatment----Lime Softening 183
8.3.1 Cold Lime Softening 184
8.3.2 Warm Lime Softening 185
8.3.3 Hot Process Softening 185
8.4 Sequencing of Pretreatment Technologies 187
References 189
PART 3 SYSTEM DESIGN
9 Design Considerations 193
9.1 Feed Water Quality 193
9.1.1 Feed Water Source 193
9.1.2 Total Dissolved Solids 196
9.1.3 Calcium and Natural Organic Matter 197
9.1.4 Chemical Damage 198
9.2 Temperature 198
9.3 Pressure 200
9.4 Feed Water Flow 201
9.5 Concentrate Flow 202
9.6 Beta 202
9.7 Recovery 205
9.8 pH 207
9.9 Flux 209
References 209
10 RO Design and Design Software 211
10.1 ROSA Version 6.1 214
10.2 TorayDS Version 1.1.44 221
10.3 Hydranautics IMS Design Version 2008 224
10.4 Koch Membranes ROPRO Version 7.0 230
Reference 234
PART 4 OPERATIONS
11 On-Line Operations 237
11.1 Reverse Osmosis Performance Monitoring 237
11.2 Data Collection 237
11.3 Data Analysis and Normalization 239
xii Contents
11.3.1 Data Normalization 239
11.3.1.1 Normalized Product Flow 240
11.3.1.2 Normalized Salt Passage 243
11.3.1.3 Normalized Pressure Drop 245
11.3.2 Normalization Software 247
11.4 Preventive Maintenance 250
References 253
12 Performance Degradation 255
12.1 Normalized Permeate Flow 255
12.1.1 Loss of Normalized Permeate Flow 255
12.1.1.1 Membrane Fouling 255
12.1.1.2 Membrane Scaling 256
12.1.1.3 Membrane Compaction 256
12.1.2 Increase in Normalized Permeate Flow 256
12.1.2.1 Membrane Degradation 256
12.1.2.2 Hardware Issues 257
12.2 Normalized Salt Rejection 258
12.2.1 Loss of Salt Rejection 258
12.2.1.1 Membrane Scaling 258
12.2.1.2 Membrane degradation 259
12.2.1.3 Hardware Issues 259
12.2.2 Increase in Salt Rejection 259
12.3 Pressure Drop 259
12.3.1 Loss in Pressure Drop 260
12.3.2 Increase in Pressure Drop 260
References 261
13 Off-Line Operations 263
13.1 System Flush 263
13.1.1 Off-Line Flush 263
13.1.2 Return to Service Flush 264
13.1.3 Stand-by Flush 265
13.2 Membrane Cleaning 266
13.2.1 When to Clean 266
13.2.2 How to Clean 267
13.2.3 Cleaning Chemicals 270
13.2.3.1 High-pH cleaners 271
Contents xiii
13.2.3.2 Neutral-pH Cleaners 272
13.2.3.3 Low-pH Cleaners 273
13.2.3.4 Cleaners for Specifi c Foulants
and Scale 274
13.2.4 Cleaning Equipment 274
13.2.4.1 Cleaning Tank 275
13.2.4.2 Cleaning Recirculation Pump 277
13.2.4.3 Cartridge Filter 277
13.3 Membrane Lay-Up 277
13.3.1 Short-Term Lay-Up 277
13.3.2 Long-Term Lay-up 278
References 278
PART 5 TROUBLESHOOTING
14 Troubleshooting 283
14.1 Mechanical Evaluation 284
14.2 General Performance Issues 285
14.3 System Design and Performance Projections 285
14.3.1 System Design 285
14.3.2 Performance Projections 286
14.4 Data Assessment 287
14.5 Water Sampling 290
14.6 Membrane Integrity Testing 291
14.7 Profi ling and Probing 291
14.8 Membrane Autopsy 294
14.8.1 Visual Inspection 295
14.8.2 Pressure Dye Test----Rhodamine B 301
14.8.3 Methylene Blue Test 301
14.8.4 Fujiwara Test 301
14.8.5 Spectroscopy 302
14.8.6 Other Tests 303
References 304
PART 6 SYSTEM ENGINEERING
15 Issues Concerning System Engineering 307
15.1 Sodium Water Softening 307
15.1.1 Sequencing of the Sodium Softeners and RO 307
15.1.2 Sodium Softening and Antiscalants 309
Case 1: High Hardness Well Water 310
xiv Contents
Sodium Softener 311
Antiscalant 311
Summary 312
Case 2: Low Hardness Surface Water 313
Sodium Softener 313
Antiscalant 313
Summary 314
Case 3: Well Water with Iron and Manganese 314
Sodium Softener 314
Antiscalant 314
15.2 Reverse Osmosis Sizing and Capacity 316
15.3 Membrane Cleaning: On-Site versus Off-Site 317
15.3.1 Off-Site Membrane Cleaning 317
15.3.2 On-Site Membrane Cleaning 318
15.4 Reverse Osmosis Reject Disposal Options 319
15.4.1 Discharge to Drain or Sewer 320
15.4.2 Discharge to Cooling Tower 320
15.4.3 Zero Liquid Discharge 321
References 323
16 Impact of Other Membrane Technologies 325
16.1 Microfi ltration and Ultrafi ltrati
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