Written by one of the most prolific and respected chemical engineers in the world and his co-author, also a well-known and respected engineer, this is the “new standard” in the industry, offering engineers and students alike the most up-do-date, comprehensive, and state-of-the-art coverage of processes and best practices in the field today.
Table of ContentsPreface
Acknowledgements
About the Authors
1. Computations with Excel Spreadsheet-UniSim Design Simulation
SECTION I - NUMERICAL ANALYSIS INTRODUCTION
Excel Spreadsheet
Functions
Trendline Coefficients
Goal Seek
SOLVER
LINEAR REGRESSION
Measuring Regression Quality
MULTIPLE REGRESSION
POLYNOMIAL REGRESSION
SIMULTANEOUS LINEAR EQUATIONS
NONLINEAR EQUATIONS
INTERPOLATIONS
INTEGRATIONS
The Trapezoidal Rule
Simpson’s 1/3 Rule
Simpson’s 3/8 Rule
DIFFERENTIAL EQUATIONS
Nth Order Ordinary Differential Equations
Solution of First-Order Ordinary Differential Equations
Runge-Kutta Methods
EXAMPLES AND SOLUTIONS
SECTION II – PROCESS SIMULATION INTRODUCTION
Thermodynamics for Process Simulators
UNISIM Design
EXAMPLES AND SOLUTIONS
References
2. Physical Property of Pure Components and MixturesPURE COMPONENTS
Density of Liquid
Viscosity of Liquid
Heat Capacity of Liquid
Thermal Conductivity of Liquid
Volumetric Expansion Rate
Vapor Pressure 89 Viscosity of Gas
Thermal Conductivity of Gas
Heat Capacity of Gases
MIXTURES
Surface Tensions
Viscosity of Gas Mixture
Enthalpy of Formation
Enthalpy of Vaporization
Gibbs Energy of Reaction
Henry’s Law Constant for Gases in Water
Coefficient of Thermal Expansion of Liquid
DIFFUSION COEFFICIENTS
Gas-Phase Diffusion Coefficients
Liquid-Phase Diffusion Coefficients
COMPRESSIBILITY Z-FACTOR
SOLUBILITY AND ADSORPTION
Solubility of Hydrocarbons in Water
Solubility of Gases in Water
Solubility of Sulfur and Nitrogen Compounds in Water
Adsorption on Activated Carbon
References
3. Fluid FlowINTRODUCTION
Flow of Fluids in Pipes
EQUIVALENT LENGTH OF VARIOUS FITTINGS AND VALVES
Excess Head Loss
Pipe Reduction and Enlargement
PRESSURE DROP CALCULATIONS FOR SINGLE-PHASE INCOMPRESSIBLE FLUIDS Friction Factor
Overall Pressure Drop
Nomenclature
COMPRESSIBLE FLUID FLOW IN PIPES
Maximum Flow and Pressure Drop
Critical or Sonic Flow and the Mach Number
Mach Number
Mathematical Model of Compressible Isothermal Flow
Flow Rate Through Pipeline
Pipeline Pressure Drop
Nomenclature
Subscripts
TWO-PHASE FLOW IN PROCESS PIPING
Flow Patterns
Flow Regimes
Pressure Drop
Erosion-Corrosion
Nomenclature
VAPOR-LIQUID TWO-PHASE VERTICAL DOWNFLOW
The Equations
The Algorithm
Nomenclature
LINE SIZES FOR FLASHING STEAM CONDENSATE
The Equations
Nomenclature
FLOW THROUGH PACKED BEDS
The Equations
Nomenclature
EXAMPLES AND SOLUTIONS
References
4. Equipment Sizing INTRODUCTION
SIZING OF VERTICAL AND HORIZONTAL SEPARATORS
Vertical Separators
Calculation Method for a Vertical Drum
Calculation Method for a Horizontal Drum
Liquid Holdup and Vapor Space Disengagement
Wire Mesh Pad
Standards for Horizontal Separators
Piping Requirements
Nomenclature
SIZING OF PARTLY FILLED VESSELS AND TANKS
The Equations
Nomenclature
PRELIMINARY VESSEL DESIGN
Nomenclature 175 CYCLONE DESIGN
Introduction
Cyclone Design Procedure
The Equations
Saltation Velocity
Pressure Drop
Troubleshooting Cyclone Maloperations
Cyclone Collection Efficiency
Cyclone Design Factor
Cyclone Design Procedure
Nomenclature
GAS DRYER DESIGN
The Equations
Pressure Drop
Desiccant Reactivation
Nomenclature
EXAMPLES AND SOLUTIONS
References
5. Instrument SizingINTRODUCTION
Variable-Head Meters
Macroscopic Mechanical Energy Balance
Variable-Head Meters
Orifice Sizing for Liquid and Gas Flows
Orifice Sizing for Liquid Flows
Orifice Sizing for Gas Flows
Orifice Sizing for Liquid Flow
Orifice Sizing for Gas Flow
Types of Restriction Orifice Plates
Case Study 1
NOMENCLATURE
CONTROL VALVE SIZING
INTRODUCTION
Control Valve Characteristics
Pressure Drop for Sizing
Choked Flow
Flashing and Cavitation
CONTROL VALVE SIZING FOR LIQUID, GAS, STEAM AND TWO-PHASE FLOWS Liquid Sizing
Gas Sizing
Critical Condition
Steam Sizing
TWO-PHASE FLOW
Installation
Noise
Control Valve Sizing Criteria
Valve Sizing Criteria
Self-Acting Regulators
Types of Self-Acting Regulators
Case Study 2
RULES OF THUMB
NOMENCLATURE
References
6. Pumps and Compressors SizingPUMPS
INTRODUCTION
Pumping of Liquids
Pump Design Standardization
Basic Parts of a Centrifugal Pump
Impellers
Casing
Shaft
CENTRIFUGAL PUMP SELECTION
Single-Stage (Single Impeller) Pumps
Hydraulic Characteristics for Centrifugal Pumps
Friction Losses Due to Flow
Velocity Head
Friction
NET POSITIVE SUCTION HEAD (NPSH) AND PUMP SUCTION
General Suction System
Reductions in NPSHR
Corrections to NPSHR for Hot Liquid Hydrocarbons and Water
Charting NPSHR Values of Pumps
Net Positive Suction Head (NPSH)
Specific Speed
“Type Specific Speed”
Rotative Speed
Pumping Systems and Performance
System Head Using Two Different Pipe Sizes in Same Line
POWER REQUIREMENTS FOR PUMPING THROUGH PROCESS LINES
Hydraulic Power
Relations Between Head, Horsepower, Capacity, Speed
Brake Horsepower (BHP) Input at Pump
AFFINITY LAWS
Pump Parameters
Specific Speed, Flowrate and Power Required by a Pump
Pump Sizing of Gas-Oil
Debutanizer Unit
CENTRIFUGAL PUMP EFFICIENCY
Centrifugal Pump Specifications
Pump Specifications
Steps in Pump Sizing
Reciprocating Pumps
Significant Features in Reciprocating Pump Arrangements
Application
Performance
Discharge Flow Patterns
HORSEPOWER
Pump Selection
Selection Rules-of-Thumb
A CASE STUDY
Pump Simulation on a PFD
Variables Descriptions
SIMULATION ALGORITHM
Problem
Discussion
Pump Cavitation
Factors in Pump Selection
COMPRESSORS
INTRODUCTION
General Application Guide
Specification Guides
GENERAL CONSIDERATIONS FOR ANY TYPE OF COMPRESSOR FLOW CONDITIONS
Fluid Properties
Compressibility
Corrosive Nature
Moisture
Special Conditions
Specification Sheet
PERFORMANCE CONSIDERATIONS
Cooling Water to Cylinder Jackets
Heat Rejected to Water
Drivers
Ideal Pressure – Volume Relationship
Actual Compressor Diagram
DEVIATIONS FROM IDEAL GAS LAWS: COMPRESSIBILITY
Adiabatic Calculations 344 Charles’ Law at Constant Pressure
Amonton’s Law at Constant Volume
Combined Boyle’s and Charles’ Laws
Entropy Balance Method
Isentropic Exponent Method
COMPRESSION RATIO
Horsepower
Single Stage
Theoretical Hp
Actual Brake Horsepower, Bhp
Actual Brake Horsepower, Bhp (Alternate Correction for Compressibility) Temperature Rise – Adiabatic
Temperature Rise – Polytropic
A CASE STUDY USING UNISIM DESIGN R460.1 SOFTWARE FOR A TWO–STAGE COMPRESSION
CASE STUDY 2
Solution
1. Starting UniSim Design Software
2. Creating a New Simulation
Saving the Simulation
3. Adding Components to the Simulation
4. Selecting a Fluids Package
5. Select the Units for the Simulation
6. Enter Simulation Environment
Accidentally Closing the PFD
Object Palette
7. Adding Material Streams
8. Specifying Material Streams
9. Adding A Compressor
Specifications
COMPRESSION PROCESS
Adiabatic
Isothermal
Polytropic
Efficiency
Head
ADIABATIC HEAD DEVELOPED PER SINGLE-STAGE WHEEL
Polytropic Head
Polytropic
Brake Horsepower
Speed of Rotation
TEMPERATURE RISE DURING COMPRESSION
Sonic or Acoustic Velocity
MACH NUMBER
Specific Speed
COMPRESSOR EQUATIONS IN SI UNITS
Polytropic Compressor
Adiabatic Compressor
Efficiency
Mass Flow Rate, w
Mechanical Losses
Estimating Compressor Horsepower
Multistage Compressors
Multicomponent Gas Streams
AFFINITY LAWS
Speed
Impeller Diameters (Similar)
Impeller Diameter (Changed)
Effect of Temperature
AFFINITY LAW PERFORMANCE
TROUBLESHOOTING OF CENTRIFUGAL AND RECIPROCATING COMPRESSORS NOMENCLATURE
Greek Symbols
Subscripts
Nomenclature
Subscripts
Greek Symbols
References
Pumps
Bibliography
References
Compressors
Bibliography
7. Mass TransferINTRODUCTION
VAPOR LIQUID EQUILIBRIUM
BUBBLE POINT CALCULATION
DEW POINT CALCULATION
EQUILIBRIUM FLASH COMPOSITION
Fundamental
The Equations
The Algorithm
Nomenclature
TOWER SIZING FOR VALVE TRAYS
Introduction
The Equations
Nomenclature
Greek Letters
PACKED TOWER DESIGN
Introduction
Pressure Drop
Flooding
Operating and Design Conditions
Design Equations
Packed Towers versus Trayed Towers
Economic Trade-Offs
Nomenclature
Greek Letters
DETERMINATION OF PLATES IN FRACTIONATING COLUMNS BY THE SMOKER EQUATIONS
Introduction
The Equations
Application to a Distillation Column
Rectifying Section:
Stripping Section:
Nomenclature
MULTICOMPONENT DISTRIBUTION AND MINIMUM TRAYS
IN DISTILLATION COLUMNS
Introduction
Key Components
Equations Surveyed
Fractionating Tray Stability Diagrams
Areas of Unacceptable Operation
Foaming
Flooding
Entrainment
Weeping/Dumping
Fractionation Problem Solving Considerations
Mathematical Modeling
The Fenske’s Method for Total Reflux
The Gilliland Method for Number of Equilibrium Stages
The Underwood Method
Equations for Describing Gilliland’s Graph
Kirkbride’s Feed Plate Location
Nomenclature
Greek Letters
EXAMPLES AND SOLUTIONS
References
Index Back to Top