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Porous Plastics

By Johannes Karl Fink
Copyright: 2022   |   Status: Published
ISBN: 9781119896388  |  Hardcover  |  
416 pages | 132 illustrations
Price: $225 USD
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One Line Description
A unique book by a well-known polymer scientist on a subject that is trending in plastics/polymer engineering.

Audience
The book will be used by plastics engineers, materials scientists and polymer scientists/researchers in both industry and academia.

Description
Porous polymers are materials that are having pores in their design. Porous polymers are important for various fields of application and are used with pores of different sizes, i.e., from macropores to micropores.
This book focuses on the issues of porous polymers as well as low molecular compounds that can be introduced in porous polymers. The book begins with a chapter about polymers that are used for porous materials. Here, among others, microporous polymer networks, hyper-crosslinked polymers, and rigid ladder-type porous polymers are detailed. Related issues are also detailed in the subsequent chapters. In the next chapter, the major synthesis methods for porous polymers are described. Then, the properties and material testing methods, such as standards, are described in a chapter. In the following chapters, special fields of applications of porous polymers are described in detail, such as: medical uses, thermal insulation, membranes, separation methods, and other fields of use.

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Author / Editor Details
Johannes Karl Fink is Professor of Macromolecular Chemistry at Montanuniversität Leoben, Austria. His industry and academic career spans more than 30 years in the fields of polymers, and his research interests include characterization, flame retardancy, thermodynamics and the degradation of polymers, pyrolysis, and adhesives. Professor Fink has published many books on physical chemistry and polymer science including A Concise Introduction to Additives for Thermoplastic Polymers (Wiley-Scrivener 2009), The Chemistry of Biobased Polymers, 2nd edition (Wiley-Scrivener 2019), 3D Industrial Printing with Polymers (Wiley-Scrivener 2019), and The Chemistry of Environmental Engineering (Wiley-Scrivener 2020).

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Table of Contents
Preface
1. Materials

1.1 Styropor
1.2 Porous Coordination Polymers
1.2.1 Multifunctional Pillared-Layer Material
1.2.2 Porous Coordination Polymer-Ionic Liquid Composite
1.3 Networks
1.3.1 Microporous Polymer Networks
1.3.2 Amorphous Microporous Polymer Networks
1.4 Rigid Ladder-Type Porous Polymers
1.5 Photocatalysts
1.5.1 Compounds for Photocatalytic Aerobic Oxidation
1.5.2 Floating Photocatalysts
1.5.3 Photocatalysts with Side Chains
References
2. Synthesis Methods
2.1 Porogens
2.1.1 Polymers and Organic Solvents
2.1.2 Water as Porogen
2.1.3 Solid Porogens
2.2 Living Radical Polymerization
2.3 Emulsion Polymerization
2.3.1 High Internal Phase Emulsion Polymerization
2.3.2 Microchannel Emulsification
2.4 Solvent-Free Polymerization
2.5 Suspension Polymerization
2.6 Multistage Polymerization Techniques
2.7 Azo Coupling
2.8 Precipitation Polymerization
2.9 Microfluidics
2.10 Photocatalysis
2.11 Thermal Drawing
2.12 Biodegradable Foam
2.13 Biocompatible Porous Three-Dimensional Polymer Matrices
2.14 Breath-Figure Method
2.14.1 Effects of the Chemical Structure of Polymers
2.14.2 Coating Layers with Selective Wettability on Filter Papers
2.15 Superabsorbent Polymers
2.16 Functionalization Methods
2.16.1 Thiol-Ene Click Chemistry
2.16.2 Ionic Bond Functionalization
2.16.3 Pore-Size-Specific Functionalization
References
3. Properties
3.1 Special Materials
3.1.1 Porous Polymer Pressure Sensors
3.1.2 Crack Propagation Behavior
3.2 Standard Test Methods
3.2.1 Polymeric Scaffolds
3.2.2 Leaks in Porous Medical Packaging
3.2.3 Pore Diameter and Permeability
3.2.4 Mercury Intrusion Porosimetry
3.2.5 Pore Size of a Membrane Filter
3.2.6 Computed Tomography
3.2.7 Water Absorption
3.2.8 Microbial Ranking of Porous Packaging Materials
3.2.9 Antibacterial Properties
3.2.10 Performance of Antimicrobials
3.2.11 Surgical Implants
3.2.12 Acoustical Properties
3.2.13 Detection of Leaks in Packaging
3.2.14 Sorbent Performance of Adsorbents
References
4. Medical Uses
4.1 Medical Diagnostics
4.1.1 Extracellular Vesicles
4.2 Medical Devices
4.2.1 Stent Grafts
4.2.2 Vascular Grafts
4.3 Medical Applications
4.3.1 Porous Polymer Microneedles
4.3.2 Flexible Pressure Sensors
4.3.3 Bone Regeneration
4.3.4 Release of Therapeutic Agents
4.3.5 Implant Dentistry
4.4 Biomedical Applications
4.4.1 Macroporous Hydrogels
4.4.2 Alginate Foams
4.4.3 Biodegradable Sponges
4.4.4 Biomedical Scaffolds
4.4.5 Biodegradable Electronic Materials
4.4.6 Optical Fibers
4.4.7 Bead Sorbent
References
5. Thermal Insulation
5.1 Prediction Models
5.2 Radiative and Conductive Heat Transfer
5.3 Studies of Thermal Conductivity
5.3.1 Macroporous Polymer-Derived SiOC Ceramics
5.4 Poly(ethylene) Foams
5.5 Rigid Foams
5.5.1 Aromatic Polymers
5.5.2 PVC
5.5.3 Poly(urethane)
5.6 Microporous Foams
5.6.1 Microporous Poly(styrene)
5.6.2 Conjugate Microporous Foams
5.7 Resilient Porous Polymer Foams
5.8 Electrically Conductive Networks
5.8.1 Poly(lactic acid)
5.8.2 Natural Rubber
5.9 Electroconducting Polymer Coatings
5.10 Foam Insulation Structure
5.11 Passive Cooling
5.11.1 Radiative Cooling
5.11.2 Passive Building Cooling
5.12 Sulfur-Containing Polymers
5.13 Nanocellular Polymers
5.13.1 Poly(methyl methacrylate) Thermoplastic Poly(urethane) Composites
5.13.2 Poly(methyl methacrylate) Multiwalled Carbon Nanotube Composites
5.14 Household Applications
5.14.1 Refrigerator
5.15 Fluid Storage Tank
5.16 Thermal Insulation for High Explosives
5.17 Aerogels
5.17.1 Polysaccharide-Based Aerogels
5.17.2 Silica Aerogels
5.17.3 Aerogel Fibers
References
6. Membranes
6.1 Cellulose Acetate
6.2 Poly(vinylidene fluoride)
6.2.1 Grafted Phosphonium Poly(vinylidene fluoride)
6.2.2 Hollow Fiber Poly(vinylidene fluoride)
6.2.3 Casting Methods
6.3 Poly(amino acid)s
6.4 Hyper-crosslinked Polymers
6.5 Membrane for Specific Molecular Separation
6.6 Treatment of Water
6.6.1 Ammonia Removal
6.6.2 Fine Pore Aeration
6.6.3 Water Contamination Treatment
6.7 Enzyme Reactors
6.7.1 Thermoresponsive Enzyme Reactor
6.7.2 Reversible pH-Control
6.7.3 UV-Responsive Enzyme Reactor
6.7.4 Kidney Mimicking
6.8 Electrolyte Membranes
6.8.1 Membranes for Fuel Cells
6.9 Membranes for Batteries
6.9.1 Membranes for Lithium-Ion Batteries
6.9.2 Membranes for Sodium-Ion Batteries
6.9.3 Vanadium Redox Flow Batteries
6.10 pH-Sensitive Gating in Membranes
References
7. Separation Methods
7.1 Chromatography
7.1.1 Solid Phase Extraction
7.1.2 Liquid Chromatography
7.1.3 Thin-Layer Chromatography
7.1.4 Gas Chromatography
7.1.5 Gel Permeation Chromatography
7.1.6 High-Performance Liquid Chromatography
7.2 Oil Spill Control
7.2.1 Polyolefins
7.2.2 Porphyrin
7.2.3 Poly(urethane) Sponge
7.2.4 Hierarchical Porous Membrane
7.2.5 Waste Polymers
7.3 Sorbents
7.3.1 Purification of Ethylene
7.3.2 Carbon Dioxide Capture
7.4 Recovery of Organic Materials
7.4.1 Adsorption of Acteoside
7.4.2 Toxic Organic Materials
7.4.3 Removal of Organic Micropollutants
7.4.4 Lysozyme Extraction
7.5 Metal Recovery
7.5.1 Rice Straw in Poly(urethane) Foams
7.5.2 Bonding of Metal-Containing Ions
7.5.3 Porous Porphyrin Polymer
7.5.4 Iminodiacetic Acid-Functionalized Polymer
7.5.5 Removal of Toxic Elements
7.5.6 Polyfunctional Sorbent Materials
References
8. Other Fields of Use
8.1 Ceramic Articles
8.2 Polymer-Modified Porous Cement
8.3 Flame Retardant Foams
8.3.1 Poly(urethane) Foam
8.4 Clay-Containing Composites
8.4.1 Tissue Engineering
8.4.2 Poly(methyl methacrylate) Composites
8.4.3 Hectorites
8.4.4 Catalyst Supports
8.5 Lubricant Additives
8.6 Cosmetic Compositions
8.7 Packaging Materials
8.7.1 Breathable Films
8.8 Char Layer
8.9 Batteries
8.9.1 Electrodes
8.9.2 Rechargeable Batteries
8.10 Light Emission
8.10.1 Porous Conjugated Polymer
8.10.2 Oxacalixarene Macrocycle
8.10.3 Tetraphenylcyclopentadiene
8.10.4 Porous Silicone
8.10.5 Light-Emitting Diodes
8.11 Sorbents
8.11.1 Porous Hyper-Crosslinked Polymers
References
Index
Acronyms
Chemicals
General Index

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Description
Author/Editor Details
Table of Contents
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