The book provides a comprehensive overview of the synthesis, modification, characterization, and application of 2D nanomaterials.
Table of ContentsPreface
Part I: Synthesis of 2D Nanomaterials
1. Top-Down Strategies Synthesis of 2D NanomaterialPranjyan Dash and Pradeep Kumar Panda
1.1 Introduction
1.2 Top-Down Strategy Synthesis Method
1.2.1 Etching
1.2.2 Mechanical Milling
1.2.3 Sputtering
1.3 Laser Ablation
1.4 Characterizations and Toxicity of 2D Nanomaterials
1.5 Conclusions
References
2. Bottom-Up Strategies for Synthesis of 2D NanomaterialNibedita Nath, Subhendu Chakroborty and Anita Routaray
2.1 Introduction
2.2 Types of 2D Nanomaterial
2.2.1 Graphene
2.2.2 MXenes
2.2.3 Black Phosphorus
2.2.4 Hexagonal Boron Nitride
2.2.5 Transition Metal Dichalcogenides
2.2.6 Graphitic Carbon Nitride
2.2.7 MOF and COF
2.3 Synthesis Strategies
2.3.1 Top-Down
2.3.1.1 Mechanical Milling
2.3.1.2 Electrospinning
2.3.1.3 Lithography
2.3.1.4 Sputtering
2.3.1.5 The Arc Discharge Method
2.3.1.6 Laser Ablation
2.3.2 Bottom-Up Method
2.3.2.1 Chemical Vapor Deposition
2.3.2.2 Sol–Gel Method
2.3.2.3 Solvothermal and Hydrothermal Methods
2.3.2.4 Soft and Hard Template and Reverse Micelle Methods
2.4 Bottom-Up Strategies for Synthesis of 2D Nanomaterial
2.5 Conclusion and Outlook
References
3. Unveiling the Intricacies: Characterization Techniques for 2D NanomaterialsSiba Soren, Subhendu Chakroborty, Rudra N. Purusottam and Amiya Ranjan Panda
3.1 Introduction
3.2 Characterization Techniques
3.2.1 XRD
3.2.2 SEM and TEM
3.2.3 Optical Microscope
3.2.4 AFM
3.2.5 XPS
3.2.6 RAMAN
3.3 Conclusion
References
Part II: Properties of 2D Nanomaterials
4. Crystal Structure, Magnetic and Mechanical Properties of 2D NanomaterialsNandini Roy
4.1 Introduction
4.2 Structure of 2D Materials
4.2.1 Graphene
4.2.2 Black Phosphorous
4.2.3 Transition Metal Dichalcogenide (TMDC)
4.3 Magnetic 2D Materials
4.4 Origin of Magnetization in 2D Materials
4.5 Mechanical Properties of 2D Nanomaterials
4.6 Conclusion
References
5. Electrical, Plasmonic, and Optical Properties of 2D NanomaterialsAnkita Subhrasmita Gadtya and Srikanta Moharana
5.1 Introduction
5.2 Overview of Two-Dimensional Nanomaterials (2D NMs)
5.3 Electrical Properties of 2D NMs
5.4 Optical Properties of 2D NMs
5.5 Plasmonic Properties of 2D NMs
5.6 Recent Applications of 2D NMs
5.6.1 2D NMs for BioMedical Application
5.6.2 2D NMs in the Field of Energy
5.6.3 2D NMs as Lubricant Additive
5.7 Challenges and Prospective
5.8 Conclusion
Acknowledgments
References
Part III: Application of 2D Nanomaterials
6. Challenges Surrounding 2D Nanomaterials and Their Application to Photocatalytic Industrial Wastewater TreatmentAnchit Modi and N. K. Gaur
6.1 Introduction
6.2 Photocatalysis for Industrial Wastewater Treatment
6.2.1 Principles of Photocatalysis
6.2.2 Photocatalytic Processes for Industrial Wastewater Treatment
6.2.3 Advantages and Limitations of Photocatalysis
6.3 2D Nanomaterials in Photocatalysis
6.3.1 Introduction to 2D Nanomaterials and Types Used in Photocatalysis
6.3.2 Key Properties and Characteristics of 2D Nanomaterials
6.3.3 Role of 2D Nanomaterials in Enhancing Photocatalytic Performance
6.4 Challenges in Utilizing 2D Nanomaterials for Photocatalytic Wastewater Treatment
6.4.1 Synthesis and Fabrication Challenges
6.4.2 Stability and Degradation Issues
6.4.3 Efficiency and Selectivity Considerations
6.4.4 Scalability and Cost-Effectiveness Challenges
6.5 Strategies to Overcome Challenges
6.5.1 Improvement of Synthesis and Fabrication Techniques
6.5.2 Enhancement of Stability and Durability
6.5.3 Optimization of Photocatalytic Performance
6.5.4 Economical and Scalable Production Methods
6.6 Case Studies and Applications
6.6.1 Examples of Successful Applications of 2D Nanomaterials
6.6.2 Case Studies in Photocatalytic Industrial Wastewater Treatment
6.6.3 Lessons Learned and Future Prospects
6.7 Conclusion
References
7. Application of 2D Nanomaterials for Energy StorageTulasi Barik and Subhendu Chakroborty
7.1 Introduction
7.2 2D Nanomaterials for Application of Lithium Ion Batteries
7.3 Application of 2D Nanomaterials in Sodium Ion Batteries
7.4 Application of 2D Nanomaterials in Potassium Ion Batteries
7.5 Applications of 2D Nanomaterials in Supercapacitors
Conclusions
References
8. Innovation in Photoinduced Antibacterial 2D NanomaterialsZubaid ul Khazir Rather, Shabnam Kawoosa, Gulam Nabi Yatoo, Mohd Asif Hajam, Sajad Ahmed Bhat and Javid Ahmed Banday
8.1 Introduction
8.2 Antibacterial Applications Based on Graphene-Induced Photostimulation
8.2.1 Nanomaterials for Antibacterial Transition-Metal Dichalcogenides/Oxides
8.2.2 Antibacterial Nanomaterials Based on Carbon Nitride
8.2.3 Antibacterial Nanomaterials Based on Black Phosphorus
8.2.4 Other 2D Antibacterial Nanomaterials
8.3 Antibacterial Mechanisms of Graphene-Based Family
8.3.1 Physical Contact Destruction
8.3.2 Oxidative Stress
8.3.3 Disruption of Bacterial Protein Interactions
8.3.4 Photo-Induced Mechanisms
8.4 Conclusion
References
9. 2D Nanomaterials for Drug Delivery SystemSyed Muzammil Munawar, Dhandayuthabani Rajendiran and Kaleel Basha Sabjan
9.1 Introduction
9.2 2D Material Biosynthesis
9.3 Encapsulation of 2D Materials
9.4 Hydrogel Encapsulation—2D Materials
9.5 2D Material Encapsulation—Liposomes
9.6 2D Supply Encapsulation—Micelle
9.7 Stimuli Responsive 2D Material SDDSs—Classification
9.8 Light-Sensitive SDDSs
9.9 Magnetic Field-Responsive SDDSs
9.10 Various Response Exhibits Diverse—Advantages/Disadvantages
9.11 2D Material SDDS Therapy—Cancer
9.12 Antibacterial
9.12.1 Central Nervous System
9.13 Orthopedic
9.14 Diabetes Mellitus
9.15 2D Materials in Intelligent Drug Delivery System—Advantages
9.16 Disadvantages
9.17 Conclusion and Future Perspective
Acknowledgements
References
10. New Technology 2D Nanomaterials for Neural Tissue EngineeringBanti Baishya, Saurav Paul, Hillol Das, Utsab Singha and Dipyaman Mohanta
10.1 Introduction
10.2 Regeneration of Tissue and Organ Repair in Nature
10.2.1 The ‘Curious Case’ of Lizard: A Nature’s Classic
10.2.2 Regenerative Capabilities of Amphibians
10.2.3 Regeneration in Humans
10.3 Nanotechnology and Neural Tissue Engineering
10.3.1 Definition of Nanotechnology
10.3.2 Synthesis of Nanomaterials or Nanoparticles
10.4 2D Nanomaterials for Tissue Engineering Application
10.4.1 Graphene-Based Nanomaterials in Tissue Engineering
10.4.2 Black-Phosphorus (BP)-Based Nanosheets in Tissue Engineering
10.4.3 Application of 2D Nanoclay in Tissue Engineering
10.5 2D Nanomaterials and Peripheral Nerve Engineering
10.5.1 Peripheral Nerve
10.5.2 Damage and Regeneration in Peripheral Nerve
10.5.3 Key Features of Nanomaterials in Neural Tissue Engineering
10.5.4 Mechanism of 2D Nanomaterial-Based Neural Regeneration
10.5.4.1 Graphene
10.5.4.2 Graphene Oxide
10.5.4.3 Black Phosphorus (BP)
10.6 Application of 2D Nanomaterials in Spinal Cord Repair
10.7 2D Nanomaterials for Drug/Gene Delivery
10.8 Challenges and Prospects
References
11. Theranostic Approach of 2D Nanomaterials in Breast CancerPravati Panda, Subhendu Chakroborty and Kaushik Pal
11.1 Introduction
11.2 Applications
Conclusion
Acknowledgments
References
12. 2D Nanomaterials for Photocatalytic Hydrogen ProductionGrandprix T. M. Kadja, St Mardiana and Arxhel S. F. Nanda
12.1 Introduction
12.2 Basics of Photocatalytic Hydrogen Production
12.3 2D Nanomaterials for Photocatalytic Hydrogen Production
12.3.1 Graphene-Based
12.3.2 Carbon Nitrides
12.3.3 Transition Metal Dichalcogenides
12.3.4 MXene
12.4 Enhancing the Photocatalytic Performance
12.5 Conclusion and Outlook
Acknowledgments
References
13. Supercapacitor Based on 2D Nanomaterials and Their HybridAnupam Kumar and Arun Rathore
13.1 Introduction
13.2 Structure Design of 2D Nanomaterial-Based Supercapacitors
13.3 2D Nanomaterials for Supercapacitor Technology
13.3.a Transition Metal Oxides (TMOs) and Transition Metal Hydroxides (TMHs)-Based Supercapacitor
13.3.a.1 Transition Metal Oxides
13.3.a.2 Transition Metal Hydroxides
13.3.b Transition Metal Carbide/Carbonitride (MXene)-Based Supercapacitor
13.3.c Transition Metal Dichalcogenide (TMD)-Based Supercapacitor
13.3.d Black Phosphorous-Based Supercapacitor
13.4 Conclusions
References
14. 2D Nanomaterials Based for Electrocatalytic ApplicationAnchit Modi, D. K. Gupta, Jitendra Malviya and N. K. Gaur
14.1 Introduction
14.1.1 Introduction to 2D Nanomaterials and Their Unique Properties
14.1.2 Motivation for Utilizing 2D Nanomaterials in Electrocatalytic Applications
14.2 Types of 2D Nanomaterials
14.2.1 Graphene
14.2.2 Dichalcogenides (TMDs)
14.2.3 Brief Overview of Their Structures and Properties
14.3 Electrocatalytic Reactions Enabled by 2D Nanomaterials
14.3.1 Oxygen Reduction Reaction (ORR)
14.3.2 Hydrogen Evolution Reaction (HER)
14.3.3 Carbon Dioxide Reduction Reaction (CO2RR)
14.3.4 Synthesis and Characterization Techniques
14.3.4.1 Synthesis Methods for 2D Nanomaterials
14.3.4.2 Characterization Techniques for 2D Nanomaterials
14.3.4.3 Relationship Between Synthesis, Structure, and Electrocatalytic
Performance
14.4 Challenges and Future Perspectives
14.4.1 Current Challenges in Utilizing 2D Nanomaterials for Electrocatalytic Applications
14.4.2 Potential Strategies to Overcome These Challenges
14.4.3 Future Directions and Emerging Trends in the Field
14.5 Conclusion
References
15. Engineering 2D Nanomaterials for Biomedical ApplicationsSwaati Sharma, Hardeep Kaur, Mansi Thakur and Shinar Athwal
15.1 Introduction
15.2 Synthesis of Nanomaterials
15.3 Nanomaterials for Cancer Treatment
15.4 Difference of 2D Materials from Bulk Materials
15.4.1 Graphene
15.4.1.1 Synthesis of Graphene
15.4.1.2 Graphene Properties
15.4.1.3 Applications of Graphene
15.4.2 Hexagonal Boron Nitride (hBN)
15.4.2.1 Hexagonal Boron Nitride (hBN) Synthesis
15.4.2.2 Properties of Hexagonal Boron Nitride (hBN)
15.4.2.3 Applications of Hexagonal Boron Nitride (hBN)
15.4.3 Transition Metal Dichalcogenides (TMDs)
15.4.3.1 Synthesis of Transition Metal Dichalcogenides (TMDs)
15.4.3.2 Transition Metal Dichalcogenides (TMDs) and its Properties
15.4.3.3 Applications of Transition Metal Dichalcogenides (TMDs)
15.5 2DNMS for Next-Generation Quantum and Electronic Devices
15.6 Functionalized Hybridization of 2D Nanomaterials
References
16. The Potential Applications of 2D Nanomaterials for Water PurificationHardeep Kaur, Swaati Sharma, Shinar Athwal, Mansi Thakur, Meenakshi Verma and Vishal Mutreja
16.1 Introduction
16.2 Contaminants Present in Water
16.3 2D Nanomaterial-Based Water Purification Membranes
16.4 Solar Desalination Membrane
16.5 Filtration Membrane
16.6 Properties of Widely Used 2DM for Water Purification
16.6.1 MXene
16.6.2 g-C3N4
16.6.3 Black Phosphorus
16.6.4 Graphene
16.6.5 h-BN
16.7 Synthesis of 2DM
16.7.1 Top-Down Approach
16.7.1.1 Liquid Exfoliation via Oxidation/Ion Intercalation/Mechanical Force
16.7.1.2 Mechanical Cleavage
16.7.1.3 Ion Exchange
16.7.1.4 Selective Etching
16.7.2 Bottom-Up Approach
16.7.2.1 Chemical Vapor Deposition
16.7.2.2 Wet-Chemical (WC) Synthesis
16.8 Adsorption of Contaminants From Water
16.8.1 Removal of Ions
16.8.2 Removal of Heavy Metals
16.9 Photocatalytic Purification of Water
16.10 Conclusion and Future Prospects
References
17. Insights into the Exciton Dynamics of Functionalized 2D Nanomaterials for Robust Photoelectrochemical Sensing ApplicationsDipyaman Mohanta, Koushik Barman, Abhinandan Mahanta, Bishal Bhuyan and Arpita Paul Chowdhury
17.1 Introduction
17.2 Basic Theory and Working Principle of Photoelectrochemical Sensing
17.3 Experimental Setup of Photoelectrochemical Cell
17.4 Importance of Photoactive Material in Photoelectrochemical Sensing
17.5 2D Nanomaterials in Photoelectrochemical Sensing
17.6 Current Challenges and Future Prospects
17.7 Conclusion
References
18. Fabrication of 2D Nanomaterials-Based BiosensorArpita Paul Chowdhury, M. Dinamani and K. S. Anantharaju
18.1 Introduction
18.2 2D Nanomaterial Synthesis Strategies
18.3 Role of 2D Materials in Biosensor
18.3.1 Electrochemical Biosensors
18.3.2 Fluorescence Biosensors
18.3.3 Colorimetric Biosensor
18.3.4 Field-Effect Transistor Biosensor
18.3.5 Surface-Enhanced Raman Spectroscopy (SERS)
18.4 Conclusions and Future Prospective
References
19. Transition Metal Dichalcogenide (TMD)-Based 2D Nanomaterials for Various Kinds of Rechargeable BatteriesPeriyakaruppan Karuppasamy and Varatharaj Rajapanian
19.1 Introduction
19.2 Synthesis of 2D-TMDCs
19.3 Applications of 2D-Transition Metal Di-Chalcogenides (2D-TMDCs) in Various Categories of Rechargeable Batteries
19.3.1 Li-Ion Batteries (LIBs)
19.3.2 Sodium-Ion Batteries
19.3.3 Potassium Ion Batteries (PIBs)
19.3.4 Magnesium Ion Batteries (MIBs)
19.3.5 Zinc Ion Batteries (ZIBs)
19.3.6 Lithium Sulfur Batteries (LSBs)
19.3.7 Aluminum Ion Batteries (AIBs)
19.4 Conclusion
References
20. Effect of 2D Nanomaterial Addition to Performance and Emission Characteristics of Diesel EngineGeetesh Goga and M. V. B. Unnamatla
20.1 Introduction
20.2 Performance Characteristics
20.3 Emission Characteristics
20.4 Conclusion
References
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