This comprehensive book describes the fundamental principles and major advancements in the utilization of agro-waste for deriving biopolymers, and their applications to fabricate composite, nanocomposite, and hybrid food packaging films and coatings.
Table of ContentsPreface
1. Promising Agro-Wastes for Food PackagingL. Susmita Devi, Avik Mukherjee and Santosh Kumar
1.1 Introduction
1.2 Current Global Status of Agro-Wastes
1.3 Types of Agro-Wastes
1.3.1 Agro-Industrial Waste
1.3.2 Crop Residues
1.3.3 Animal Waste
1.3.4 Aquatic Waste
1.4 Extraction of Biopolymers from Agro-Wastes
1.4.1 Chemical Treatment
1.4.1.1 Acid Treatment
1.4.1.2 Alkali Treatment
1.4.1.3 Organic Solvent Treatment
1.4.2 Biological Treatment
1.4.3 Mechanical Processing
1.4.4 Thermochemical Processing
1.5 Extraction of Bioactive Compounds from Agro-Wastes
1.6 Conclusion and Future Perspectives
References
2. Natural Fiber–Based Composite for Food PackagingRishika Bora, Hemanta Chutia, Monika, Murchana Changmai, Charu Lata Mahanta, Vimal Katiyar and Tabli Ghosh
2.1 Introduction
2.2 Fiber Types
2.2.1 Natural Fibers
2.2.1.1 Plant-Based Fibers
2.2.1.2 Animal-Based Fibers
2.2.2 Man-Made Fibers
2.3 Plant Fiber–Based Composite for Food Packaging
2.3.1 Wood-Based Composite for Food Packaging
2.3.2 Stem/Bast-Based Composite for Food Packaging
2.3.2.1 Kenaf Fiber
2.3.2.2 Jute Fiber
2.3.2.3 Ramie Fiber
2.3.2.4 Hemp Fiber
2.3.3 Leaf-Based Composite for Food Packaging
2.3.3.1 Palm Fiber
2.3.3.2 Sisal Fiber
2.3.3.3 Pineapple Leaf Fiber
2.3.3.4 Banana Fiber
2.3.4 Seed/Fruit-Based Composite for Food Packaging
2.3.5 Grass-Based Composite for Food Packaging
2.3.5.1 Bamboo Fiber
2.3.5.2 Rice Husk and Wheat Straw
2.4 Animal Fiber–Based Composite for Food Packaging
2.4.1 Silk-Based Composite for Food Packaging
2.4.2 Wool-Based Composite for Food Packaging
2.4.3 Other Animal Fiber-Based Composite
2.5 Nanomaterials from Natural Fiber
2.6 Natural Fiber–Based Composite for Circular Economy
2.7 Conclusion and Future Perspective
Acknowledgment
References
3. Corncob Waste for Food PackagingAntony Catherine Flora Louis and Sivakumar Venkatachalam
3.1 Introduction
3.2 Isolation of Cellulose from Corncob
3.2.1 Pretreatment of Corncob Waste Residues
3.2.1.1 Acidic Hydrolysis
3.2.1.2 Alkaline Treatment
3.2.2 Bleaching Process
3.2.3 Extraction of Nanocellulose
3.3 Isolation of Hemicellulose from Corncob
3.4 Microbial Biosynthesis of Polyhydroxy Butyrate (PHB) from Corncobs
3.5 Biopolymers-Based Food Packaging Reinforced with Corncob Fibers
3.6 Hybrid Nanocomposite of Corncob for Food Packaging
3.7 Conclusion and Future Perspectives
References
4. Coir Fibers for Sustainable Food PackagingSweety Kalita, Manashi Das Purkayastha, Avik Mukherjee and Santosh Kumar
4.1 Introduction
4.2 Coir Fibers as Reinforcement Material for Synthetic Polymers
4.2.1 Polyethylene-Based Composites Reinforced with Coir Fibers
4.2.2 Polypropylene-Based Composites Reinforced with Coir Fibers
4.2.3 Polyester-Based Composites Reinforced with Coir Fibers
4.3 Coir Fibers as Reinforcement Material in Biopolymers
4.3.1 Composites of Coir and Polylactic Acid (PLA)
4.3.2 Composites of Coir and Protein
4.3.3 Composites of Coir with Starch
4.3.4 Hybrid Composites of Coir
4.4 Biodegradable Package/Container from Coconut Coir
4.5 Conclusion and Future Perspective
References
5. Sugarcane Bagasse for Sustainable Food PackagingSweety Kalita, Avik Mukherjee and Santosh Kumar
5.1 Introduction
5.2 Chemical Composition and Characteristics of Sugarcane Bagasse (SB)
5.3 Cellulosic and Hemicellulosic Fractions of Sugarcane Bagasse
5.4 Pretreatment Approaches for SB
5.4.1 Physical Pretreatments
5.4.1.1 Mechanical Pretreatment
5.4.1.2 Microwave Pretreatment (MWP)
5.4.1.3 Ultrasound Pretreatment (USP)
5.4.2 Chemical Pretreatments
5.4.2.1 Acidic Pretreatment (AP)
5.4.2.2 Alkaline Treatment
5.4.2.3 Ionic Liquids Pretreatment
5.4.3 Physiochemical Pretreatment
5.4.3.1 Organosolv Pretreatments
5.4.3.2 Steam Explosion Pretreatment
5.4.3.3 Hot Water Pretreatments
5.4.4 Biological Treatment
5.5 Sugarcane Bagasse in Biopolymer Matrix as Reinforcement Filler
5.6 Food Containers and Trays Made From SB
5.7 Conclusion and Future Perspective
References
6. Husk and Straw of Cereals Grains for Sustainable Food PackagingPooja Baiju, Maria Jose Mukkadan and Preetha Radhakrishnan
Abbreviations
6.1 Introduction
6.2 Extraction and Purification of Cellulose from Husk and Straw
6.2.1 Pretreatment Methods
6.2.2 Purification Methods
6.2.2.1 Alkali Treatment
6.2.2.2 Bleaching
6.2.3 Extraction Methods
6.3 Cellulose Nanocrystals
6.3.1 Modifications and Functionalization of CNC
6.3.2 Applications of CNC in Packaging Films
6.4 Use of Cellulose and Its Derivatives in Food Packaging
6.4.1 Cellulose Ethers
6.4.1.1 Ethyl Cellulose (EC) and Methyl Cellulose (MC)
6.4.1.2 Carboxymethyl Cellulose (CMC)
6.4.1.3 Hydroxyethyl Cellulose (HEC)
6.4.1.4 Hydroxypropyl Cellulose (HPC)
6.4.2 Cellulose Esters
6.4.2.1 Cellulose Acetate (CA)
6.4.2.2 Cellulose Nitrate (CN)
6.4.2.3 Cellulose Sulfate (CS)
6.5 Paper-Based Package from Straw and Husk
6.6 Tableware and Food Containers from Straw and Husk
6.6.1 Compostable and Biodegradable Tableware and Containers
6.6.2 Wheat Straw Plastic
6.7 Conclusion and Future Perspective
References
7. Sericulture Waste for Edible Films and Coating of Fruits and VegetablesSweety Kalita, Avik Mukherjee and Santosh Kumar
7.1 Introduction
7.2 Sericulture Wastes
7.3 Extraction and Purification of Silk Protein/Fibroin
7.4 Silk Protein–Based Active Food Packaging
7.4.1 Silk Protein/Fibroin–Based Active Films
7.4.2 Silk Protein/Fibroin–Based Edible Coating
7.5 Toxicological and Food Allergy Assessment of Silk Protein/Fibroin
7.6 Conclusion and Future Perspective
References
8. Functional Agents from Agro-Waste for Active and Intelligent Food PackagingLokesh Kumar, Ram Kumar Deshmukh and Kirtiraj K. Gaikwad
8.1 Introduction
8.2 Functional Agents in Active and Intelligent Packaging
8.2.1 Polyphenolic Compounds from Agro-Waste
8.2.1.1 Polyphenolic Compounds from Apple Peel
8.2.1.2 Polyphenolic Compounds from Citrus Fruit
8.2.1.3 Polyphenolic Compounds from Potato Peel
8.2.1.4 Polyphenolic Compounds from Pineapple Peel
8.2.1.5 Polyphenolic Compounds from Mango Kernel
8.2.1.6 Polyphenolic Compounds from Grape
8.2.1.7 Polyphenolic Compounds from Pomegranate Peel
8.2.1.8 Polyphenolic Compounds from Banana Peel
8.2.1.9 Polyphenolic Compounds from Corncob
8.2.1.10 Polyphenolic Compounds from Wheat Straw
8.2.2 Antioxidants from Agro-Waste
8.2.2.1 Antioxidant Compounds from Apple Peel
8.2.2.2 Antioxidant Compounds from Citrus Fruit
8.2.2.3 Antioxidant Compounds from Potato Peel
8.2.2.4 Antioxidant Compounds from Pineapple Peel
8.2.2.5 Antioxidant Compounds from Mango Kernel
8.2.2.6 Antioxidant Compounds from Grape Pomace
8.2.2.7 Antioxidant Compounds from Pomegranate Peel
8.2.2.8 Antioxidant Compounds from Banana Peel
8.2.2.9 Antioxidant Compounds from Corncob
8.2.2.10 Antioxidant Compounds from Wheat Straw
8.2.3 Antimicrobials Compounds from Agro-Waste
8.2.3.1 Antimicrobials Compounds from Pomegranate Peel
8.2.3.2 Antimicrobials Compounds from Grape Pomace
8.2.3.3 Antimicrobials Compounds from Mango Kernel
8.2.3.4 Antimicrobials Compounds from Citrus Fruit
8.2.3.5 Antimicrobials Compounds from Banana Peel
8.2.3.6 Antimicrobials Compounds from Pineapple Peel
8.2.4 Biobased Indicators
8.3 Active and Intelligent Agents in Biopolymer-Based Food Packaging
8.3.1 Oxygen and Carbon Dioxide Indicators
8.3.2 Moisture or Humidity Indicator
8.3.3 pH Indicators
8.3.4 Temperature Indicator
8.3.5 Specific Chemical Indicator
8.4 Conclusion and Perspective
References
9. Starch from Agro-Waste for Food Packaging ApplicationsShashank T. Mhaske, Jyoti Darsan Mohanty and Pavan Y. Borse
9.1 Introduction
9.2 Starch from Agro-Waste
9.2.1 Tuber Wastes
9.2.2 Seed Wastes
9.3 Modifications in Starch for Food Packaging
9.3.1 Chemical Modification
9.3.1.1 Acetylation
9.3.1.2 Acid Chloride Modification
9.3.1.3 Octenyl Succinic Anhydride (OSA) Modification
9.3.1.4 Hydropropylation
9.3.1.5 Oxidation of Starch
9.3.1.6 Cross-Linking of Starch
9.3.2 Physical Modification of Starch to Thermoplastic Starch (TPS)
9.4 Starch-Based Composite, Nanocomposite, and Hybrid Films
9.4.1 Starch-Based Blends
9.4.2 Starch-Based Composite and Nanocomposite
9.5 Food Packaging Applications
9.6 Conclusion and Perspectives
References
10. Chitosan from Agro-Waste for Food Packaging ApplicationsMekala Pavani, Sushil Kumar Singh and Poonam Singha
List of Abbreviations
10.1 Introduction
10.2 Sources of Chitosan
10.2.1 Agro-Waste
10.2.2 Sources Other Than Agro-Waste
10.2.2.1 Terrestrial Insects
10.2.2.2 Microbial Sources
10.2.2.3 Marine Sources
10.3 Chitosan Extraction
10.4 Chitosan and Its Functional Properties
10.4.1 Antimicrobial Activity
10.4.2 Antioxidant Properties
10.4.3 Film-Forming Ability
10.4.4 Solubility
10.5 Chitosan-Based Composites and Nanocomposites
10.5.1 Coating Formulations
10.5.2 Packaging Films
10.6 Food Packaging Applications
10.6.1 Fish and Meat Products
10.6.2 Fruits and Vegetables
10.7 Conclusion and Future Perspectives
References
11. Biodegradable Synthetic Poly(Lactic Acid) (PLA) for Food Packaging ApplicationShikha Sharma, Tabli Ghosh, Neha Mulchandani and Vimal Katiyar
11.1 Introduction
11.2 Synthesis of PLA
11.3 Properties of PLA
11.3.1 Composites of PLA
11.3.2 Stereocomplex of PLA
11.3.2.1 Stereocomplex PLA
11.3.2.2 Additives to Enhance Stereocomplexation of PLA
11.4 Food Packaging Applications of PLA
11.5 Conclusion and Future Prospects
References
12. Pectin from Agro-Waste Residues for Food PackagingKona Mondal and Vimal Katiyar
12.1 Introduction
12.2 Structure and Classification of Pectin
12.2.1 Structure of Pectin
12.2.2 Classifications of Pectin
12.3 Agro-Waste as Sources of Pectin
12.4 Techniques for Pectin Extraction from Agro-Waste
12.4.1 Hydrothermal Extraction
12.4.2 Ultrasound-Assisted Extraction
12.4.3 Hydrodynamic Cavitation
12.4.4 Microwave-Assisted Extraction
12.4.5 Subcritical Water Extraction
12.4.6 Enzyme-Assisted Extraction
12.5 Food Packaging Applications of Pectin-Based Films and Coatings
12.5.1 Pectin-Based Active Films
12.5.1.1 Film Fabrication by Casting
12.5.1.2 Film Fabrication by Spraying
12.5.1.3 Film Fabrication by Extrusion
12.5.2 Pectin-Based Active Coatings
12.5.2.1 Preservation of Fruits and Vegetables
12.5.2.2 Preservation of Meat, Poultry, and Aquatic Animal Products
12.6 Conclusion and Perspective
References
13. Cellulosic Nanomaterials and Its Derivatives from Agro-Waste for Food Packaging ApplicationsRahul Ranjan, Rohit Rai, Vikash Kumar, Smruti B. Bhatt and Prodyut Dhar
13.1 Introduction
13.2 Cellulose Structure and Its Nano-Derivatives
13.2.1 Hemicellulose
13.2.2 Xylan
13.2.3 Mannans (Mannoglycans)
13.2.4 Xyloglucan
13.2.5 β-Glucan
13.2.6 Holocellulose
13.2.7 Bacterial Cellulose
13.3 Agro-Waste as Source of Cellulose
13.4 Extraction of Cellulose from Agro-Waste
13.5 Cellulose-Derived Biopolymers
13.5.1 Carboxymethyl Cellulose (CMC)
13.5.2 Cellulose Acetate (CA)
13.5.3 Cellulose Nanofiber (CNF)
13.6 Food Packaging Applications of Cellulose and Its Derivatives
13.7 Conclusion and Perspective
References
14. Biodegradability of BiopolymersAnamika Nayak and Debjani Dutta
14.1 Introduction
14.2 Biodegradability of Traditional Food Packaging
14.3 Biodegradability of Biopolymers
14.3.1 Cellulose-Based Biopolymers
14.3.2 Starch-Based Biopolymers
14.3.3 Protein-Based Biopolymers
14.3.4 Polylactide (PLA)
14.3.5 Polyhydroxybutyrate (PHB)
14.3.6 Polyhydroxybutyrate-Co-Valerate (PHBV)
14.4 Mechanisms and Pathways of Biopolymer Degradation
14.4.1 Abiotic Degradation
14.4.2 Biodeterioration and Depolymerization
14.4.3 Biofragmentation
14.4.4 Assimilation and Mineralization
14.5 Biodegradation of Biopolymer-Based Food Packaging
14.5.1 Microbial Degradation
14.5.2 Enzymatic Degradation
14.6 Conclusion and Perspective
References
15. Migration Concerns of Biopolymer-Based Food PackagingVikramsingh Thakur and Bhabani K. Satapathy
15.1 Introduction
15.2 Migration Concerns of Biopolymer-Based Nanocomposite
15.2.1 Starch-Based Nanocomposites
15.2.2 PLA-Based Nanocomposites
15.2.3 Polyhydroxyalkanoates (PHA)-Based Nanocomposites
15.3 Migration of Oligomers From Biopolymers in Contact with Food
15.4 Migration of Nanomaterials
15.4.1 Silver Nanoparticle–Incorporated Biopolymer Composite Films
15.4.2 Clay-Based Biopolymer Films
15.4.3 Other Nanomaterials as Fillers in Biopolymer Films
15.5 Biopolymer-Based Nanocomposite Films and Coatings
15.6 Effect of Polymer and Migrant Geometry on Migration
15.7 Diffusion Modeling of Migration in Food Packaging
15.8 Conclusion and Future Perspectives
References
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