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Novel Anti-Corrosion and Anti-Fouling Coatings and Thin Films

Edited by Hari Murthy, Vinay Jha Pillai, Kukatlapalli Pradeep Kumar and Matthew Cowan
Copyright: 2024   |   Expected Pub Date: //
ISBN: 9781394234288  |  Hardcover  |  
523 pages
Price: $225 USD
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One Line Description
The book showcases the current state of the technology by providing an understanding of the anticorrosive and anti-biofouling effects of nanomaterials and nanocomposites under different environments; the chapters span a wide range of topics, reflecting the interdisciplinary nature of organic coatings and materials science.

Audience
The book can be used as a standard reference for manufacturers of antifouling solutions, the shipping industry, oil and gas producers, aquaculture, and other industries using offshore structures. Researchers and engineers working in corrosion engineering, metal surface and coatings engineering, materials science, chemical engineering, and applied chemistry will find this book to be very useful.

Description
Nanomaterials and nanocomposite materials have been developed as corrosion inhibitors and are the most noble and effective alternatives to traditional organic corrosion inhibitors. Nanomaterials provide reasonably high anticorrosive activity in both aqueous and solution phases. A unified approach to this task is lacking, however, which highlights the role of all disciplines involved in the creation and use of corrosion protection coatings for metals. Fouling is the process of accumulating unwanted material that is mostly non-living and comprised of detritus and organic or inorganic compounds, or organisms, such as tiny viruses up to giant
kelps. This book covers both the processes of biofouling and anti(bio)fouling, and the devices that stop the biofouling process.
This book provides a missing synopsis by providing an understanding of the anticorrosive and anti-biofouling effects of nanomaterials and nanocomposites under different environments. It features an up-to-date picture of the quality and chemistry of a substrate surface, its proper preparation by conversion treatment, the function of resins and anticorrosive pigments in paints, and novel concepts for corrosion protection.

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Author / Editor Details
Hari Murthy, PhD, is a faculty member in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Bengaluru, India. His doctoral thesis from the University of Canterbury, New Zealand was on novel anticorrosion materials. He has published several articles in international journals and conferences.

Vinay Jha Pillai, PhD, is an assistant professor in the Department of Electronics and Communication Engineering, CHRIST (Deemed to be University), Kengeri Campus, Bangalore, India. His primary research is in the early detection of breast cancer using optical imaging and holds two patents related to the subject. He is also exploring the domain of sensors for extracting coating parameters, especially for thermal barrier coatings which have a wide application in the
field of corrosion and biofouling inhibitors.

Kukatlapalli Pradeep Kumar, PhD, is an associate professor and data science program coordinator at Christ University, Bangalore, India. One of his research areas is in the field of data science for corrosion engineering where novel methods for corrosion inhibition based on data science techniques for correlating simulation predictions and molecular structures are in high demand.

Matthew Cowan, PhD, is a faculty member in the Department of Chemical and Processing Engineering at the University of Canterbury, New Zealand. As a materials chemist, his main research interests are in the application of ionic liquids and ionic polymers for anti-fouling applications as well as efficient process designs for industrial gas separations. He is the author of more than 30 publications.

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Table of Contents
Preface
Acknowledgements
1. Antifouling Nanoparticle Coatings for Post-Harvest Food Preservation

Gokuraju Thriveni, Hari Murthy and CH. Anusha
1.1 Introduction
1.2 Materials Support Post-Harvest
1.3 Computational Methods to Envision the Interaction of Food Residuals with Coated Nanolayers Through Sensing
1.4 Feasible Research Implications to Address the Shortcomings in Food Preservation
References
2. Toward Stable Electrochemical Water Splitting: Anticorrosive Properties of Transition Metal–Based Electrocatalytic Coatings
Kaushal Gavankar, Suchitra Sapakal and Anamika V. Kadam
2.1 Introduction
2.2 Corrosion Mechanisms
2.3 Methods to Prevent Corrosion
2.3.1 To Avoid pH Attack
2.3.2 Material Selection
2.3.3 Surface Functionalization
2.3.4 Protective Coating Deposition
2.3.5 Corrosion Engineering
2.4 Anticorrosive Catalytic Coating
2.4.1 FeO
2.4.2 MoO2-Based Coating
2.4.3 NiO-Based Coating
2.4.4 Ni-Fe on Iron Foam (IF)
2.4.5 NiFeN
2.4.6 NiFeBx
2.4.7 Gd-Mn3O4@CuO-Cu (OH)2 Nanostructure
2.4.8 Cobalt-Based Coatings
2.4.9 Cr2O3@CoOx
2.5 Carbon-Based Anticorrosive Catalytic Coatings
2.5.1 Carbon-Based Coatings
2.6 Discussion
2.6.1 Stability Characterization
2.6.2 Future Prospects and Challenges
2.7 Conclusion
Acknowledgement
References
3. Ionic Liquids in Marine Anti-Fouling Coatings
Samantha Taylor, Sajith K. Baiju, Madison K. McQuinlan and Matthew G. Cowan
3.1 Introduction
3.1.1 Societal, Environmental, and Economic Context to Marine Biofouling
3.1.2 Mechanism of Biofouling
3.1.2.1 Stage 1: Conditioning Film Formation
3.1.2.2 Stage 2: Primary Colonization
3.1.2.3 Stage 3: Secondary Colonization
3.1.2.4 Stage 4. Secondary Colonization
3.1.3 Factors Affecting Speed and Extent of Biofouling
3.1.3.1 Seasonal Factors: Temperature and Sunlight
3.1.3.2 Pollution
3.1.4 Background of Anti-Fouling Coatings
3.1.4.1 Heavy Metal Biocide Coatings
3.1.4.2 Heavy Metal Substitutes
3.2 Current Anti-Fouling Design Strategies
3.2.1 Requirements of Novel Anti-Fouling Coating
3.2.1.1 Performance Specifications
3.2.1.2 Necessary Considerations
3.2.2 Types of Anti-Fouling Coatings
3.2.2.1 Foul Degrading Coatings
3.2.2.2 Foul-Resistant Coatings
3.2.2.3 Fouling Release Coatings
3.2.3 Summary of Anti-Fouling Strategies and Opportunity for Ionic Liquids
3.3 Poly(Ionic Liquids) as Anti-Fouling Coatings
3.3.1 Experimental Methods for Evaluating Poly(Ionic Liquid) Coatings
3.3.1.1 Anti-Bacterial Activity
3.3.1.2 Micro-Algae Inhibition
3.3.1.3 Immersion Testing (Macrofoulers)
3.3.2 Anti-Fouling Performance of Poly(Ionic Liquids)
3.3.2.1 Immersion Testing (Macrofoulers)
3.3.2.2 Micro-Algae Inhibition
3.3.3 Ionic Liquid Properties for Anti-Fouling
References
4. Inorganic Nanomaterial Coating to Prevent Biofouling
Anju T. R., Mariat George and Rose Mary Jose
4.1 Introduction
4.2 Major Industries Affected by Biofouling
4.3 Conventional Antifouling Coatings and their Demerits
4.4 Nanomaterials as Antifoulants: Properties and Mechanisms
4.5 Types of Nanomaterials Used as Antifoulants
4.6 Inorganic Nanomaterials as Antifoulant
4.6.1 Silver Nanoparticles
4.6.2 Oxides of Ti and Zn
4.6.3 Metals Like Gold, Copper, and Selenium
4.6.4 Graphene
4.6.5 Carbon Nanotubes
4.7 Impact and Challenges of Inorganic Nanomaterials as Antifoulants
4.8 Conclusion
References
5. Thin Film Transparent Conducting Oxides and its Anticorrosion and Surface Protection Applications: A Review
Balaprakash V., Thangavel K., Mahitha Mohan, Gowrisankar P. and Sakthivel R.
5.1 About Transparent Conducting Oxides
5.2 Electrical Properties of TCOs
5.3 Optical Properties of TCO
5.4 Need of TCO for Solar Cells and Optoelectronic Devices
5.5 Requirements of TCO
5.6 Commonly Used TCO Materials
5.7 Application of TCOs
5.8 Anti-Corrosion and Surface Protection Application of Doped Zinc Oxide–Based TCO Materials
5.9 NZO Coating Over Stainless Steel
5.9.1 Materials Used for Synthesis
5.9.2 Synthesis of Nickel-Doped ZnO Nanostructured Thin Films
5.9.3 Structural Properties of NZO Thin Films Coated Over Stainless Steel
5.9.4 Morphological Properties of NZO Thin Films Coated Over Stainless Steel
5.9.5 Optical Properties of NZO Thin Films Coated Over Stainless Steel
5.9.6 Anticorrosion and Surface Protection Applications of NZO Thin Films
5.10 Conclusion
References
6. Integrated Anticorrosion and Antifouling Coatings
Ankita Kumari, Nirmala Kumari Jangid, Sudesh Kumar, Rekha Sharma and Navjeet Kaur
6.1 Introduction
6.2 Mechanisms of Corrosion and Biofouling
6.2.1 Biofouling Mechanisms
6.2.2 Corrosion Mechanisms
6.3 Recent Developments in Integrated Anticorrosion Coatings and Antifouling Coatings
6.3.1 Polyaniline-Based Coatings
6.3.1.1 PANI Coatings/Organic Biocides
6.3.1.2 PANI/Nanoparticle Composites
6.3.1.3 Antibacterial Epoxy/PANI Composites
6.3.1.4 Epoxy Coatings /PANI Derivatives
6.3.2 Copper/Amorphous Carbon Coatings
6.3.3 Polydopamine/Polymer Brushes
6.3.4 Amphiphilic Polymers
6.3.5 Endospore-Loaded Sol-Gel Coatings
6.3.6 Corrosion-Inhibiting Hydrophobic Coatings
6.3.7 Nanocomposites
6.3.8 Bioinspired Coatings
6.3.8.1 Superhydrophobic Surfaces
6.3.8.2 Slippery Liquid-Infused Porous Surfaces (SLIPS)
6.4 PNCs Nanocoatings (Polymer Nanocomposites Coatings)
6.4.1 Biocides Used as Antifouling Agents
6.4.2 Poly(2-Hydroxyethyl Methacrylate) (PHEMA) Hydrogel Film as Antifouling Alternative
6.5 Marine Environment Durability Test of IAACs
6.6 Evaluation of Various IAACs and Difficulties
6.7 Conclusion and Outlook
Conflict of Interest
Research Funding
Acknowledgements
References
7. EIS Study of Anticorrosive Nanocomposite Films
Vandana Shinde
7.1 Importance of Organic-Inorganic Nanocomposite Coatings
7.2 EIS: Brief Basic Principle and Introductions
7.2.1 Brief History
7.2.2 Significance of EIS
7.2.3 Basic Principle
7.2.4 Impedance Measurement Techniques
7.2.4.1 Instrumentation
7.2.4.2 Comparisons Between Various Techniques for Impedance Measurement
7.3 EIS Data Analysis: Fitting the Equivalent Electronic Circuit, Introduction of the Various Circuit Parameters Its Physics
7.3.1 EIS Data Introduction
7.3.1.1 Dielectric Spectroscopy
7.3.2 Electrochemical Experiment and Transportation of Charges
7.3.3 The Prospect of Electrochemistry
7.3.4 Uncertainty in Impedance Data Analysis
7.3.5 Data Fitting of EIS Spectra
7.3.5.1 Nonlinear Least Squares Method for EIS Fitting
7.3.5.2 Deconvolution of Spectra
7.3.6 Equivalent Circuits and Its Components
7.3.6.1 Equivalent Circuit
7.3.6.2 Electrolyte Resistance
7.3.6.3 Double-Layer Capacitance
7.3.6.4 Charge Transfer Resistance
7.3.6.5 Frequency-Dependent Elements
7.4 EIS in Anticorrosive Modern Nanocomposite Coatings and Assessment of Corrosion Protection Performance
7.4.1 Introduction
7.4.2 Corrosion Mechanism
7.5 Conclusions
References
8. Graphene-Based Coating on Mild Steel for Improving Anticorrosion and Microhardness Behavior: A Review
Sunita Dhar, Tapan Dash, Ashok Kumar Sahu, Sushree Subhadarshinee Mohapatra, Nibedita Mohanty, Shubhra Bajpai, Tapan Kumar Rout and Surendra Kumar Biswal
8.1 Introduction of Graphene
8.1.1 General Uses of Graphene Derivatives
8.1.2 Different Types of Typical Graphene Derivatives
8.2 Synthesis Mechanism of Graphene Derivatives
8.3 Typical Characterizations of Graphene Derivatives
8.3.1 Evaluation of Properties of Graphene Derivatives by XRD
8.3.2 Evaluation of Morphological Behavior of Graphene Derivatives by SEM
8.3.3 Evaluation of Morphological Behavior of Graphene Derivatives by TEM and SAED
8.3.4 Raman Spectroscopic Behavior of Graphene Derivatives
8.3.5 Evaluation of Properties of Graphene Derivatives by BET Specific Surface Area and Electrical Conductivity
8.4 Anticorrosion Mechanisms of Graphene Derivatives and Their Composites
8.5 Anticorrosion Behavior of Graphene Derivative Coating on Mild Steel
8.6 Microhardness Behavior of Graphene Derivative Coating on Mild Steel
8.7 Conclusions
References
9. Bioinspired Strategies for Corrosion Protection and Antifouling Coatings
K. R. C. Soma Raju, Aarti Gautam, Ramay Patra, K. Srinivasa Rao, K.V. Gobi and R. Subasri
9.1 Introduction
9.1.1 Types of Fouling Based on Factors Contributing to Fouling
9.1.2 Methods to Prevent Fouling
9.1.3 Recent Developments in the Area of Antifouling Coatings
9.1.4 Bioinspired Strategies for the Development of Functional Coatings
9.1.5 Methods to Generate Bioinspired Surfaces with Emphasis on Sol-Gel Technology
9.1.5.1 Bioinspired, Sol-Gel–Based Antifouling Coatings
9.1.5.2 Bioinspired Sol-Gel–Based Anticorrosion Coatings
9.1.6 About Antifouling Paint Particles (APP)
9.2 Conclusions
Acknowledgement
References
10. Implementation of Nanotechnology in Anticorrosion Material Development for Food Packaging
Aparna Ray Sarkar, Dwaipayan Sen and Pramita Sen
10.1 Introduction
10.2 Synthesis of Nanoclay-Based Composites for Food Packaging
10.2.1 Halloysite-Based Nanocomposites
10.2.2 Montmorillonite-Based Composites
10.3 Metal Nanoparticle-Based Composites
10.4 Synthesis of Biopolymer-Based Packaging Material
10.5 Structural Features of Different Nanocomposites
10.5.1 Nanoclay
10.5.2 Chitosan Nanoparticles (CNPs)
10.5.3 Titanium Dioxide Nanomaterials (TiO2 NPs)
10.5.4 Silver Nanoparticles (Ag NPs)
10.5.5 Zinc Oxide Nanocomposite (ZnO NPs)
10.5.6 Carbon Nanotubes (CNTs)
10.6 Application of Different Nanomaterials in Canned Food Packaging
10.7 Concluding Remark
References
11. Development and Characterization of Nanostructured Thin Films for Corrosion Control Applications
M. Geetha Devi, R. Senthilkumar and Hebatallah Al Jabri
11.1 Introduction
11.2 Various Forms of Corrosion in the Petroleum Industry
11.2.1 Environmental Cracking or Caustic Embrittlement
11.2.2 Fretting Corrosion
11.2.3 High-Temperature Corrosion
11.2.4 Pitting Corrosion
11.2.5 Crevice Corrosion
11.2.6 Galvanic Corrosion
11.2.7 Stress Corrosion
11.2.8 Intergranular Corrosion
11.2.9 Erosion Corrosion
11.2.10 Sweet (CO2) Corrosion
11.2.11 Uniform Corrosion
11.2.12 Microbiologically Influenced Corrosion (MIC)
11.3 Corrosion’s Effects on Various Equipment Used in the Petrochemical Industry
11.3.1 Heat Exchanger
11.3.1.1 Different Forms of Corrosion in Heat Exchangers
11.3.2 Crude Distillation Overhead System
11.4 Conventional Corrosion Control Techniques
11.4.1 Engineering Design
11.4.2 Selection of Material for Construction
11.4.3 Coatings
11.4.4 Cathodic Protection
11.4.5 Corrosion Inhibitors
11.5 The Role of Nanotechnology in Corrosion Control
11.5.1 Types of Nanocoatings Employed in Corrosion Control
11.5.1.1 Ceramic Nanocoatings
11.5.1.2 Alumina Nanocoatings
11.5.1.3 Tantalum Oxide Nanocoatings
11.5.1.4 Zirconium Oxide Nanocoatings
11.5.1.5 Graphene Oxide Nanocoatings
11.5.1.6 Nanocomposite Coatings
11.5.1.7 Metallic Nanocoating
11.6 Application of Nanocomposite Thin Films in Corrosion Control
11.6.1 Materials and Methods
11.6.2 Synthesis of TiO2 Nanoparticles and Preparation of Coating Solution
11.6.3 Fabrication of Nanocomposite and Thin Film Stability Studies
11.6.4 Corrosion Inhibition Studies of PANI-TiO2–Coated Specimen
11.7 Results and Discussion
11.8 Conclusion
11.9 Future Scope
11.10 Challenges
References
12. Anticorrosion and Antifouling Coating Materials
N. Haridharan and R. V. Shiva Kumar
12.1 Introduction
12.1.1 Demerits of Using Bare Metallic Components as a Substrate Material in Marine Applications
12.1.2 Essentiality in Designing and Developing Novel Materials for Anticorrosive and Antifouling Purposes
12.1.3 The Serious Effects of Marine Organisms and Salty Water on the Surface of Marine Infrastructure and How It Affects Marine Construction and Transport
12.1.4 The Advantages of Protective Coatings on the Surface of the Material to Overcome this Difficulty
12.1.5 Coating Thickness—A Good Alternative But Yet…
12.1.6 Coating Integrity
12.1.7 Choosing the Right Coating Material
12.1.8 Factors to be Considered While Choosing a Protective Coating
12.1.9 Regular Inspection and Maintenance
12.2 Key Issues in the Formulation of Anticorrosive Materials
12.3 Formulating a Good Model for Leaching
12.4 The Advent of Nanotechnology
12.5 Summary of the Current Developments
12.6 Conclusion
Bibliography
13. Metal(II) Complexes as Potential Anticorrosion and Antifouling Agents—A Review
Asha M. S., Zabiulla, Othbert Pinto, Arjun S. R., Alen Eldose and Sangamesha M. A.
13.1 Introduction
13.2 Outline and Mechanism of Metal(II) Complexes as Corrosion Inhibitors
13.2.1 Comparison of Corrosion Rate and Inhibition Efficiency
13.3 Outline of Metal Complexes as Antifouling Agents
13.3.1 The Outcome of Barnacle Larvae Bioassay for Ligand and Its Complexes
13.4 Conclusion
Acknowledgements
References
14. Thermodynamic Modeling of Carbonaceous Coating of Oxides and Sulfides Thin Films Grown by CVD for Enhancing Surface Quality
Kranthi Kumar Vaidyula, Sukanya Dhar, Anjali Lalithambika and S. A. Shivashankar
14.1 Introduction
14.2 Experimental
14.2.1 Thermodynamic Modeling
14.2.1.1 Al2O3 Growth
14.2.1.2 MoS2 Growth
14.2.2 Characterization
14.3 Results and Discussion
14.3.1 Thermodynamic Calculations for Al2O3 and Growth
14.3.2 Thermodynamic Modeling and Growth of MoS2
14.4 Conclusions
References
15. Metal Nanoparticles: Biosynthesis Approach and Bio-Packaging Application
Priti Chaware, Amol Nande, J. D. Punde, K. G. Rewatkar and S. J. Dhoble
15.1 Introduction
15.2 Synthesis of NPs
15.3 Characterization of Nanoparticles
15.3.1 X-Ray Diffraction (XRD)
15.3.2 UV-Visible Absorption Spectroscopy
15.3.3 FE-Scanning Electron Microscopy (FESEM)
15.3.4 EDS
15.3.5 HR-TEM
15.3.6 FT-IR Spectroscopy
15.3.7 Application of Biosynthesized Nanoparticles for Bio-Packaging
15.4 Concluding Remarks
References
16. Statistical Data Analysis of Anticorrosion and Antifouling: Unveiling Insights from Performance and Trends
Preetham Noel P., Kukatlapalli Pradeep Kumar, Mani Joseph P. and Vinay Jha Pillai
16.1 Introduction
16.2 Literature
16.2.1 Tetrabromobisphenol-A Epoxy and Polyaniline Nanowires Coating
16.2.2 AZ31 Magnesium Alloy Fabrication by Establishing Superhydrophobic Needle-Like Ca-P Layering
16.2.3 Cerium Stearate Surfaces – Fluorine-Free
16.2.4 Corrosion and Biofouling – Marine Microorganisms
16.2.5 Fluorinated Silica Is Classified as Superamphiphobic and Exhibits a Core-Shell Framework
16.3 Results and Discussion
16.4 Conclusion
References
17. Comprehensive Data Analysis of Anticorrosion, Antifouling Agents, and the Efficiency of Corrosion Inhibitors in CO2 Pipelines
Vineeth Simhadri, Kukatlapalli Pradeep Kumar, Vijaya P. and Vinai George Biju
17.1 Introduction
17.2 Literature Review
17.2.1 Superoleophobic Composite Coating
17.2.2 Recent Advancements in Nanotechnological Research Related to Nanocomposite Coatings for Applications in Anticorrosion, Antifouling, and Self-Healing
17.2.3 Rapid Curing and Self-Stratifying Lacquer Coatings
17.2.4 Poly(Aniline-Co-Nitroaniline) Nanoparticle Coatings
17.2.5 Emerging Integrated Anticorrosion and Antifouling Coatings
17.3 Results and Discussion
17.4 Conclusion
References
Index

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