This book is a comprehensive reference manual that contains essential information on thermoforming processing and technology.
Table of ContentsPreface
1. Introduction
2. Polymers 2.1 Introduction
2.2 Physics and Chemistry of Polymers
2.3 Natural Polymers
2.4 Synthetic Polymers
2.5 Polymerization Methods
2.5.1 Addition Polymerization
2.5.2 Condensation Polymerization
2.6 Polymer Molecules in Thermoforming
2.7 Classification
2.8 Primary Classification
2.8.1 Homopolymers
2.8.2 Copolymers
2.8.2.1 Block Copolymers
2.8.2.2 Diblock Copolymers
2.8.2.3 Multiblock Copolymers
2.8.3 Alternating Copolymers
2.8.4 Random Copolymers
2.8.5 Graft Copolymers
2.8.6 Impact Copolymers
2.9 Secondary Classification
2.9.1 Thermoplastics
2.9.2 Thermosetting Plastics
2.10 Distinction Between Thermoplastics and Thermosetting
2.11 General Classification
2.11.1 Commodity Plastics
2.11.2 Engineering Plastics
3. Thermoplastics3.1 Introduction
3.2 Polyolefins
3.3 Polyethylene
3.3.1 Low Density Polyethylene (LDPE)
3.3.2 High-Density Polyethylene (HDPE)
3.3.3 Linear-Low-Density Polyethylene (LLDPE)
3.4 Polypropylene
3.5 Polystyrene (PS)
3.6 High-Impact Polystyrene (HIPS)
3.7 Polyvinylchloride
3.8 Acrylonitrile–Butadiene–Styrene (ABS)
3.9 Polyethylene Terephthalate (PET)
3.10 Acrylics
3.10.1 Polymethylmethacrylate (PMMA)
3.11 Nylon 6 (PA6)
3.12 Nylon 66 (PA66)
3.13 Polyoxymethylene (POM)
3.14 Polycarbonate (PC)
3.15 Poly(ether-ether-ketone) (PEEK)
3.16 Polyphenylene Oxide (PPO)
3.17 Polybutylene Terephthalate (PBT)
3.18 Liquid Crystalline Polymers
3.19 Cyclic Olefin Copolymer (COC)
3.20 Plastic Foams
3.21 Thermoplastic Elastomers
3.21.1 Thermoplastic Olefin (TPO)
3.21.2 Thermoplastic Urethane (TPU)
3.22 Thermoplastic Composites (TCs)
3.23 Bioplastics
3.23.1 Polylactic Acid (PLA)
3.23.2 Poly(Butylene Succinate) (PBS)
4. Properties of Thermoplastic Sheet Materials 4.1 Introduction
4.2 Polymer Characteristics
4.3 Polymer Morphology
4.3.1 Amorphous Polymers
4.3.2 Semi-Crystalline Polymers
4.3.3 Crystalline Polymers
4.3.4 Amorphous Versus Semi-Crystalline Polymers
4.4 Molecular Structure
4.5 Molecular Weight
4.6 Molecular Weight Distribution
4.7 Melt Flow Index
4.8 Glass Transition Temperature
4.9 Melt Temperature
4.10 Heat Deflection Temperature (HDT)
4.11 Crystallization Temperature
4.12 Melt Strength
4.13 Rheological Properties
4.14 Viscoelastic Behavior
4.15 Coefficient of Friction
4.16 Thermal Conductivity
4.17 Thermal Diffusivity
4.18 Specific Heat
4.19 Stress
4.20 Strain Hardening
4.21 Plastic Strain
4.22 Tensile Strain
4.23 Tensile Yield Stress
4.24 Deformation
4.25 Stress Deformation
4.26 Modulus and Stiffness
4.27 Sag
4.28 Toughness
4.29 Effect of Additives
5. Thermoforming Technology5.1 Introduction
5.2 Thermoplastic Sheet Materials
5.3 Mechanical Characteristics
5.4 Thermoformability
5.5 Thermoforming Cycle
5.6 Draw Ratio
5.7 Processing Window
5.8 Mold
5.9 Mold Design
5.10 Heating Elements
5.10.1 Infrared Heaters
5.10.2 Flash Heaters
5.10.3 Forced Convection Hot Air Heating
5.10.4 Other Heaters
5.11 Plug Material
5.12 Plug Design
5.13 Product Design
5.14 Clamping
5.15 Process Control
5.16 Process Variables
5.17 Thermal History
5.18 Pre-Drying
5.19 Plug Movement
5.20 Plug Speed
5.21 Sheet Temperature
5.22 Mold Temperature
5.23 Forming Temperature
5.24 Wall Thickness Distribution
5.25 Sheet Deformation
5.26 Heat Transfer
5.27 Effects of Temperature Distribution
5.28 Effect of Drawing
5.29 Effect of Frictional Force
5.30 Effect of Plug-Assist/Vacuum
5.31 Effect of Applied Pressure
5.32 Effect of Heating
5.33 Effect of Cooling
5.34 Rate of Deforming
5.35 Rate of Sagging
5.36 Effect of Air Temperature
5.37 Effect of Air Pressure
5.38 Effect of Crystallinity and Morphology
5.39 Processing Technology
5.39.1 Heating Stage
5.39.2 Sheet Heating
5.39.3 Forming Stage
5.39.4 Draw Ratio
5.39.5 Cooling Stage
5.40 Thermoforming—Processing of Thermoplastic Sheet Material
5.41 Methods of Thermoforming
5.42 Low-Pressure Forming Technology
5.42.1 Basic Vacuum Forming
5.43 Plug-Assist Thermoforming
5.43.1 Plug-Assist Vacuum Forming
5.44 Pressure Forming
5.44.1 Plug Assist–Air Pressure Thermoforming
5.45 Snapback Thermoforming
5.46 Drape Forming
5.47 Matched Mold Forming
5.48 Foam Sheet Forming
5.49 In-Line Thermoforming
5.50 Industrial Versus Laboratory Thermoforming
6. Troubleshooting Thermoforming6.1 Introduction
6.2 Product Quality Analysis
6.3 Product Quality
6.4 Product Defects
6.5 Fundamental and Inherent Defects
6.6 Troubleshooting
6.6.1 Blisters or Bubbles
6.6.2 Webbing/Bridging
6.6.3 Excessive Sheet Sag
6.6.4 Pinhole or Rupturing
6.6.5 Uneven Sag
6.6.6 Part Sticks to the Mold
6.6.7 Stretch Marks
6.6.8 Nipple on the Mold Side of the Thermoformed Part
6.6.9 Pock Marks
6.6.10 Poor Wall Thickness
6.6.11 Uneven Edges
6.6.12 Tearing Sheet When Forming
6.6.13 Bad Definition at the Edge
6.6.14 Glossy Spots
6.6.15 Warpage
6.6.16 Cracking in Corners
6.6.17 Raised Corners
6.6.18 Surface Marking
6.6.19 Corners Too Thin
6.6.20 Folds, Webbing, or Wrinkles
6.6.21 Part Deforms During Demolding
6.6.22 Poor Part Detail
6.6.23 Excessive Post Shrinkage
7. Thermoforming—Optimization7.1 Introduction
7.2 Thermoforming
7.3 Optimization Process
7.4 Numerical Modeling
7.5 Constitutive Model
7.6 Key Findings—Modeling
7.6.1 Selection of Material
7.6.2 Wall Thickness
7.7 Mold
7.8 Thermoforming Process
7.9 Viscoelastic Behavior
7.10 Method of Thermoforming
7.11 Heating
7.12 Cooling
7.13 Computer Simulation
7.14 Polyflow
7.15 PAM-FORM™ Software
7.16 Geometric Element Analysis (GEA)
8. Case Studies8.1 Introduction
8.2 Case Studies—Brief Details
8.3 Case Study I
8.3.1 Challenge
8.3.2 Problem Statement
8.3.3 In-Depth Analysis
8.3.4 Quantitative and Qualitative Data
8.3.5 Findings
8.3.6 Immersive Chronicle
8.4 Case Study II
8.4.1 Issue
8.4.2 Problem Statement
8.4.3 In-Depth Analysis
8.4.4 Analysis of Quantitative and Qualitative Data
8.4.5 Customer Satisfaction and Appreciation
8.4.6 Findings
8.4.7 Captivating Account
8.5 The Significance of Case Studies in Thermoforming
9. Applications9.1 Introduction
9.2 World of Thermoformed Products
9.2.1 Packaging
9.2.2 Agriculture
9.2.3 Appliances and Consumer Goods
9.2.4 Analytical and Laboratory Equipment
9.2.5 Automotive and Aerospace Industry
9.2.6 Blister Packaging
9.2.7 Building/Construction Products
9.2.8 Electrical and Electronics
9.2.9 Health-Care Packaging
9.2.10 Medical Applications
9.2.11 Packaging
9.2.12 Semiconductor Industry
9.2.13 Signs/Displays
9.2.14 Sports and Recreation
9.2.15 Transportation
9.2.16 Waste Management
9.2.17 Water Filtration Systems
9.2.18 Industrial Applications
9.2.19 Marine and Watercraft Industry
9.3 Market Trends
9.3.1 Current Market
9.3.2 Future Market
10. Conclusion
References
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